{"id":"W2949421865","doi":"10.1002/chin.201322118","title":"ChemInform Abstract: Regio‐ and Stereoselective Allylation and Crotylation of Indoles at C2 Through the Use of Potassium Organotrifluoroborate Salts.","year":2013,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Stereoselectivity; Potassium; Regioselectivity; Organic chemistry; Stereochemistry; Medicinal chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000149187,0.0001906411,0.0002498284,0.00004288386,0.00009298314,0.00005613306,0.0001035719,0.0001875864,0.00125343],"category_scores_gemma":[0.000436623,0.0001518557,0.00004781008,0.0002194057,0.0002711948,0.0008464193,0.0001288503,0.000137135,0.000005681371],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001110218,"about_ca_system_score_gemma":0.00007561397,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002084128,"about_ca_topic_score_gemma":0.00001510168,"domain_scores_codex":[0.9987913,3.478271e-7,0.0005655329,0.0001980034,0.0002771511,0.0001677136],"domain_scores_gemma":[0.9981148,0.0004346205,0.0006420679,0.0003258993,0.000425102,0.000057511],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003414486,0.0001082601,0.00793436,0.001641691,0.0002771264,7.022538e-7,0.009974478,0.0000308854,0.5567773,0.001222547,0.02734567,0.3943455],"study_design_scores_gemma":[0.0006480828,0.00001581337,0.01897288,0.00007534919,0.00004997942,0.00001930294,0.0004535935,0.0001806972,0.9668387,0.000423858,0.01214118,0.0001805824],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7972727,0.0003624739,0.00009789265,0.0004621118,0.00009009296,0.0006741289,0.0001020602,0.0000890045,0.2008495],"genre_scores_gemma":[0.9804952,0.0001584157,0.0009518157,0.0001130532,0.00008968326,0.00004984702,0.0003504994,0.00003480333,0.01775669],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4100614,"threshold_uncertainty_score":0.9996595,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0387892132584226,"score_gpt":0.2625273566262929,"score_spread":0.2237381433678703,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}