{"id":"W2949445881","doi":"10.1002/chin.200942174","title":"ChemInform Abstract: Rh‐Catalyzed Intramolecular Olefin Hydroacylation: Enantioselective Synthesis of Seven‐ and Eight‐Membered Heterocycles.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Hydroacylation; Intramolecular force; Enantioselective synthesis; Olefin fiber; Catalysis; Combinatorial chemistry; Rhodium; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002654049,0.0003506149,0.0004798221,0.0001272847,0.0001058782,0.0000554273,0.0002518952,0.000301738,0.002892034],"category_scores_gemma":[0.0006357853,0.0003596717,0.000176447,0.0003254331,0.0001603657,0.0003966176,0.00007368936,0.0002310261,0.00002731645],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001972839,"about_ca_system_score_gemma":0.0001209121,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002075317,"about_ca_topic_score_gemma":0.000002293514,"domain_scores_codex":[0.9980083,2.425858e-7,0.0007794502,0.0003880115,0.0004606349,0.0003633799],"domain_scores_gemma":[0.998329,0.000289291,0.0004658864,0.0005235677,0.0002068117,0.0001854779],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001965428,0.0001718295,0.00009376789,0.000459219,0.0001866949,0.000007881435,0.0009273196,0.000007466601,0.3050683,0.0005798869,0.002342793,0.6899583],"study_design_scores_gemma":[0.0007466594,0.00001272528,0.00147245,0.0001290645,0.00009371606,0.00007447694,0.0001845235,0.0001752377,0.9883468,0.0006078584,0.007765967,0.0003905781],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.1203463,0.0002479285,0.00004588105,0.0001787484,0.00006815161,0.0001957094,0.00008758448,0.0001504524,0.8786793],"genre_scores_gemma":[0.9924634,0.00007357065,0.0005497886,0.00009122301,0.0001350977,0.00003398979,0.0003748816,0.00003219479,0.006245833],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.8724334,"threshold_uncertainty_score":0.9998855,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01140844586528851,"score_gpt":0.2459799661114315,"score_spread":0.234571520246143,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}