{"id":"W2949450445","doi":"10.1002/chin.200502101","title":"A Highly Diastereoselective MgI<sub>2</sub>‐Mediated Ring Expansion of Methylenecyclopropanes.","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Ring (chemistry); Combinatorial chemistry; Stereochemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001119186,0.0003453282,0.000421369,0.0001406902,0.00008517403,0.00002360233,0.000276745,0.0002899076,0.0001590074],"category_scores_gemma":[0.000193177,0.0003386594,0.0001748983,0.0003690686,0.00008359579,0.0002929154,0.0001284802,0.0003627643,0.0001380952],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004098714,"about_ca_system_score_gemma":0.0002039182,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004723171,"about_ca_topic_score_gemma":0.00003336653,"domain_scores_codex":[0.9980966,7.734036e-7,0.0005617497,0.0003869294,0.0004911479,0.0004628188],"domain_scores_gemma":[0.9986516,0.00009016036,0.0003667729,0.0004673802,0.0002352001,0.0001888825],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006381811,0.00005388788,0.00001913216,0.0003206891,0.00004847048,0.00001187537,0.00160109,0.00000773027,0.8928223,0.0001120606,0.00002095854,0.1049179],"study_design_scores_gemma":[0.001444845,0.00004646212,0.00008519423,0.0001756307,0.00004899092,0.00005067643,0.001413637,0.00001013347,0.994727,0.0002792344,0.001352954,0.0003652264],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8617986,0.0001627322,0.00004961135,0.00002568916,0.0001250441,0.0001547081,0.00002860871,0.0002625604,0.1373924],"genre_scores_gemma":[0.9988006,0.0001319659,0.0002828152,0.00003449473,0.00013793,0.0000665329,0.000150173,0.0000638327,0.0003316884],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1370607,"threshold_uncertainty_score":0.9999065,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00984545524414771,"score_gpt":0.2162960066920668,"score_spread":0.2064505514479191,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}