{"id":"W2949452206","doi":"10.1002/chin.201547190","title":"ChemInform Abstract: Optimization of Reaction and Substrate Activation in the Stereoselective Cross‐Coupling of Chiral 3,3‐Diboronyl Amides.","year":2015,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Stereoselectivity; Substrate (aquarium); Coupling reaction; Coupling (piping); Combinatorial chemistry; Computational chemistry; Stereochemistry; Organic chemistry; Catalysis; Composite material","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008956451,0.001199911,0.0004396235,0.0005022426,0.0002991722,0.0005581261,0.0004926757,0.0004051024,0.0032091],"category_scores_gemma":[0.0005141784,0.0003990314,0.0001905379,0.0005305037,0.0002724875,0.0004963396,0.0003324613,0.0006104105,0.001695009],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005428125,"about_ca_system_score_gemma":0.0009591134,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001090547,"about_ca_topic_score_gemma":0.004037489,"domain_scores_codex":[0.9995267,0.00009077735,0.00003869526,0.00009489228,0.0001164384,0.0001325207],"domain_scores_gemma":[0.999831,0.00004048274,0.00005511526,0.00001451604,0.00002635388,0.00003260311],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001332409,0.0004364526,0.0006570527,0.00030778,0.00004186696,0.0002318385,0.00009260808,0.002086955,0.9735772,0.0008561397,0.0007089637,0.01967078],"study_design_scores_gemma":[0.00008087519,0.0006005994,0.0009142758,0.00001448079,0.00003541987,0.0001529255,0.00001966638,0.001167889,0.9939219,0.00006054655,0.003011552,0.00001981737],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9512786,0.003014346,0.01821996,0.0002303821,0.00008261367,0.0003205936,0.001542335,0.0005630836,0.02474796],"genre_scores_gemma":[0.9873021,0.001624575,0.007843709,0.00005224852,0.00001231668,0.00007020742,0.0008219579,0.0001027274,0.002170185],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0032091,"threshold_uncertainty_score":0.01073557,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02710236068626471,"score_gpt":0.2835235266457222,"score_spread":0.2564211659594575,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}