{"id":"W2949454454","doi":"10.1002/chin.201621090","title":"ChemInform Abstract: Stereospecific Rhodium‐Catalyzed Allylic Substitution with Alkenyl Cyanohydrin Pronucleophiles: Construction of Acyclic Quaternary Substituted α,β‐Unsaturated Ketones.","year":2016,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Queen (butterfly); Stereospecificity; Allylic rearrangement; Art history; Art; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002223322,0.0005759613,0.0007225315,0.0002875407,0.0001478278,0.00007148555,0.0006249524,0.0004191225,0.001847863],"category_scores_gemma":[0.0001438429,0.0003919448,0.0002613311,0.0007788101,0.0006883842,0.0009881916,0.0001085494,0.0002344628,0.0001676871],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003855262,"about_ca_system_score_gemma":0.0002037659,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001036352,"about_ca_topic_score_gemma":0.00001509258,"domain_scores_codex":[0.9969372,2.988156e-7,0.001110178,0.0006005684,0.0007274618,0.0006242999],"domain_scores_gemma":[0.9972275,0.0001685742,0.0009892044,0.001034087,0.0003242177,0.0002564122],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006244613,0.0001880143,0.002510057,0.0004357455,0.0004052162,0.00002345949,0.0003599218,3.734501e-7,0.2671449,0.0003555955,0.0003373154,0.727615],"study_design_scores_gemma":[0.001960925,0.00002157341,0.003139951,0.0004533665,0.0001633428,0.0001299773,0.0005245713,0.00001046311,0.9864138,0.00003673165,0.006517002,0.0006283394],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6992304,0.0001641743,0.000009170082,0.00008330255,0.0001106201,0.0002202551,0.0001077906,0.0002368819,0.2998374],"genre_scores_gemma":[0.9946601,0.0002706459,0.0001417596,0.00001123739,0.0001875732,0.00008572123,0.0004482799,0.00005822796,0.00413645],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.7269866,"threshold_uncertainty_score":0.9998533,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01299685784013529,"score_gpt":0.2114632663976658,"score_spread":0.1984664085575305,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}