{"id":"W2949457307","doi":"10.1002/chin.200606270","title":"Catalytic Asymmetric Esterification of Ketenes","year":2006,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Catalysis; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003069724,0.0007380022,0.000367874,0.0005432845,0.0003367465,0.0003680545,0.0005892046,0.0003800053,0.009360111],"category_scores_gemma":[0.0002832459,0.0001727802,0.0003467709,0.0004106506,0.0002478708,0.0009426707,0.0007292909,0.0009779773,0.003281395],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004097287,"about_ca_system_score_gemma":0.0005176826,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006317833,"about_ca_topic_score_gemma":0.001116293,"domain_scores_codex":[0.9997366,0.00002533526,0.00001694395,0.0000387296,0.00005201216,0.0001304355],"domain_scores_gemma":[0.9999387,0.00001020706,0.000006989939,0.0000114572,0.00001521902,0.0000172752],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009387024,0.0005410977,0.0004152237,0.001998048,0.0001170525,0.002469155,0.0007420703,0.003160565,0.8501151,0.03331888,0.008590964,0.09759313],"study_design_scores_gemma":[0.00005947062,0.0001973014,0.0004623111,0.00004454123,0.00003500735,0.0004495022,0.00009024137,0.001147975,0.9642861,0.001379438,0.03181626,0.00003180132],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7037317,0.00709293,0.03935659,0.001075012,0.00180958,0.0003559671,0.001987288,0.0005490361,0.2440419],"genre_scores_gemma":[0.9676054,0.003511865,0.002942388,0.0001690399,0.00006697453,0.00004759135,0.0005635788,0.00005461274,0.02503864],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009360111,"threshold_uncertainty_score":0.03131264,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00916230954239752,"score_gpt":0.2080718923274092,"score_spread":0.1989095827850117,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}