{"id":"W2949459399","doi":"10.1021/ol016278t","title":"Mild Oxidative One-Pot Allyl Group Cleavage","year":2001,"lang":"en","type":"article","venue":"Organic Letters","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":55,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Periodate; Hydroxylation; Aldehyde; Vicinal; Oxidative cleavage; Cleavage (geology); Oxidative phosphorylation; Bond cleavage; Medicinal chemistry; Allylic rearrangement; Protecting group; Diol; Stereochemistry; Organic chemistry; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004605484,0.0009504891,0.0007337074,0.0004338167,0.0006302927,0.0002947185,0.001231531,0.0005032135,0.005379766],"category_scores_gemma":[0.0003139243,0.0003429952,0.0003041235,0.0003812472,0.0002691705,0.0006834662,0.0008136387,0.001087703,0.002826888],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003724426,"about_ca_system_score_gemma":0.0008197598,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001266267,"about_ca_topic_score_gemma":0.003491533,"domain_scores_codex":[0.9994691,0.00006743179,0.00003246112,0.0001032571,0.0001560018,0.0001719048],"domain_scores_gemma":[0.999892,0.0000168021,0.00001671761,0.00002037721,0.00002101806,0.00003312055],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002434476,0.0001724633,0.0001369833,0.0005907628,0.00005445401,0.0003332363,0.00006810147,0.0003686298,0.9670721,0.001442792,0.005489547,0.02402738],"study_design_scores_gemma":[0.00008547445,0.0004529773,0.001072511,0.00002501501,0.00003623799,0.0005959751,0.00002619886,0.0007442033,0.9604051,0.0004936638,0.03601613,0.00004640337],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5422475,0.02129165,0.3266331,0.002292211,0.002269835,0.002610816,0.01336696,0.007901204,0.08138667],"genre_scores_gemma":[0.8966357,0.01192114,0.05955345,0.0005621915,0.0001820954,0.0006887149,0.007110428,0.0002066876,0.02313953],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005379766,"threshold_uncertainty_score":0.01799709,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01577350284383296,"score_gpt":0.2065275172783147,"score_spread":0.1907540144344818,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}