{"id":"W2949463845","doi":"10.1002/chin.201252092","title":"ChemInform Abstract: Construction of α‐Amido‐indanones via Formal Allenamide Hydroacylation—Nazarov Cyclization.","year":2012,"lang":"en","type":"article","venue":"ChemInform","topic":"Organic and Inorganic Chemical Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Hydroacylation; Formal synthesis; Combinatorial chemistry; Stereochemistry; Organic chemistry; Catalysis; Rhodium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001460064,0.0003022041,0.0003301991,0.00007065878,0.0001507351,0.00002531343,0.0002615621,0.0003710751,0.01198081],"category_scores_gemma":[0.00021794,0.0002995712,0.0001744164,0.0002465269,0.0002137428,0.00157791,0.000124814,0.000317663,0.0001684188],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002522129,"about_ca_system_score_gemma":0.00009320013,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002883033,"about_ca_topic_score_gemma":0.000002657626,"domain_scores_codex":[0.9979685,5.933063e-8,0.0008139035,0.0001972311,0.000405195,0.0006151048],"domain_scores_gemma":[0.9985065,0.0001143802,0.0004940478,0.0004504233,0.0001553883,0.0002792524],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006270938,0.0002842796,0.00240156,0.0005063937,0.000164977,6.104525e-7,0.001398481,9.729883e-7,0.5504156,0.002130112,0.004860374,0.4377739],"study_design_scores_gemma":[0.0005524474,0.000007163239,0.001201542,0.00004717831,0.00006265318,0.00008363387,0.0007489477,0.00005529002,0.96442,0.0001826884,0.03230559,0.0003328875],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.1447726,0.0001495637,0.00002274047,0.00005681891,0.0002218114,0.00008931524,0.00003637902,0.0001607186,0.8544901],"genre_scores_gemma":[0.9893534,0.0001163867,0.0001882731,0.00004664523,0.0005090693,0.00001845212,0.0003708054,0.00004022996,0.009356706],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.8451334,"threshold_uncertainty_score":0.9999456,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009340812331863225,"score_gpt":0.2198587262288189,"score_spread":0.2105179138969556,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}