{"id":"W2949475504","doi":"10.1002/chin.200548103","title":"Mercaptopropyl‐Modified Mesoporous Silica: A Remarkable Support for the Preparation of a Reusable, Heterogeneous Palladium Catalyst for Coupling Reactions.","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Palladium; Mesoporous silica; Catalysis; Mesoporous material; Coupling reaction; Coupling (piping); Palladium catalyst; Heterogeneous catalysis; Chemical engineering; Organic chemistry; Metallurgy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001583726,0.000316573,0.0001292192,0.0002394854,0.0001483716,0.0002244898,0.000494948,0.0003821531,0.001293537],"category_scores_gemma":[0.0002739736,0.0002486164,0.0001458488,0.0001330419,0.0001857177,0.000307327,0.0002238341,0.0004996046,0.0009612446],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001791866,"about_ca_system_score_gemma":0.0002206853,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004096532,"about_ca_topic_score_gemma":0.001438513,"domain_scores_codex":[0.9998968,0.000009270389,0.000007562216,0.0000221865,0.00004663273,0.00001759578],"domain_scores_gemma":[0.9999137,0.0000197775,0.00001724166,0.00001802105,0.000011696,0.00001953572],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003530282,0.00001357266,0.00007022278,0.00004505626,0.00001058067,0.00008431606,0.00001099917,0.00005517077,0.9957873,0.0002805894,0.0003758058,0.003231155],"study_design_scores_gemma":[0.00001278011,0.00007020585,0.0009773092,0.000006715154,0.00002078658,0.0002835401,0.000009267044,0.000516657,0.9926803,0.0001100741,0.005304559,0.000007805948],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9357778,0.007430407,0.03389863,0.0008581468,0.0003787993,0.00007887563,0.00128614,0.001130891,0.01916027],"genre_scores_gemma":[0.9815866,0.001828777,0.01151511,0.0001409616,0.00008044794,0.00002916192,0.0008358784,0.00008987328,0.003893072],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001293537,"threshold_uncertainty_score":0.004327297,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02189706099633125,"score_gpt":0.296123039700679,"score_spread":0.2742259787043477,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}