{"id":"W2949477851","doi":"10.1002/chin.200512069","title":"Highly Efficient Two‐Step Synthesis of C‐sp<sup>3</sup>‐Centered Geminal Diiodides.","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Geminal; Chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001900973,0.0004366084,0.0002599328,0.0001739719,0.0001956878,0.0002992789,0.000625519,0.0002606589,0.002909282],"category_scores_gemma":[0.000201614,0.0001700155,0.0001428252,0.0002192352,0.0001634793,0.0003440642,0.0004605995,0.0004959177,0.0009720317],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004166408,"about_ca_system_score_gemma":0.0003957436,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000344058,"about_ca_topic_score_gemma":0.0009298309,"domain_scores_codex":[0.9999189,0.00001024209,0.000006125577,0.00001857325,0.00001940025,0.00002677058],"domain_scores_gemma":[0.999964,0.000007238721,0.000007030241,0.000006557732,0.000006269079,0.000008905077],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004182523,0.00006783621,0.0001768278,0.0005770203,0.00003545965,0.0002958215,0.0001751668,0.0009807479,0.9415684,0.01081883,0.00535259,0.03953311],"study_design_scores_gemma":[0.00007561497,0.0002073545,0.0002381084,0.0000124193,0.00001636521,0.0002982024,0.00004466988,0.001761207,0.9704343,0.001045585,0.02584632,0.00001983736],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7605069,0.008788674,0.1424738,0.0008749873,0.0008205319,0.0004878984,0.003494493,0.001546452,0.08100633],"genre_scores_gemma":[0.9515794,0.002445514,0.03227611,0.0001784283,0.00003152511,0.0001451948,0.001030832,0.0001846311,0.01212837],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002909282,"threshold_uncertainty_score":0.009732485,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01727759187860704,"score_gpt":0.2631010510491418,"score_spread":0.2458234591705348,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}