{"id":"W2949488607","doi":"10.1002/chin.200716065","title":"The First Catalytic Sakurai Reaction of N‐Alkoxycarbonylamino Sulfones with Allyltrimethylsilane.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemistry; Catalysis; Combinatorial chemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003341135,0.0006492303,0.0003306706,0.0003764392,0.0003753889,0.0002520889,0.0008300961,0.0004292312,0.002841253],"category_scores_gemma":[0.0003943678,0.0003649928,0.0003737808,0.0003093368,0.0004404087,0.0007168839,0.0007683939,0.001021008,0.001918621],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003869359,"about_ca_system_score_gemma":0.0005615047,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009216206,"about_ca_topic_score_gemma":0.001640906,"domain_scores_codex":[0.9997358,0.00003539994,0.00001845755,0.0000466488,0.00007475423,0.00008894708],"domain_scores_gemma":[0.999895,0.00001808198,0.00002727904,0.00002057316,0.00001497856,0.00002404164],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003019797,0.0001088362,0.000384445,0.001124932,0.0001022498,0.000813031,0.0005893215,0.0003534095,0.9061027,0.004925488,0.01345536,0.0717383],"study_design_scores_gemma":[0.0000448052,0.0003584336,0.001173276,0.00004433205,0.00005140455,0.0008365594,0.00007804804,0.0004321563,0.9289196,0.0005876889,0.06743671,0.00003703905],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.7264984,0.05380503,0.0954469,0.002916873,0.004611943,0.000719494,0.001503223,0.002025831,0.1124723],"genre_scores_gemma":[0.9302383,0.01543686,0.01874238,0.0004023408,0.0002129198,0.0001949269,0.0009935375,0.0001968462,0.03358182],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.002841253,"threshold_uncertainty_score":0.009504974,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01090376737244416,"score_gpt":0.2442566800226285,"score_spread":0.2333529126501843,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}