{"id":"W2949497093","doi":"10.1021/ol4003338","title":"Silver-Promoted, Palladium-Catalyzed Direct Arylation of Cyclopropanes: Facile Access to Spiro 3,3′-Cyclopropyl Oxindoles","year":2013,"lang":"en","type":"article","venue":"Organic Letters","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":94,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"","keywords":"Chemistry; Palladium; Catalysis; Combinatorial chemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001032681,0.0003751302,0.0001565289,0.0001246131,0.0001069454,0.0001548187,0.0003371045,0.0001729592,0.001436369],"category_scores_gemma":[0.00008893944,0.0001511978,0.0001679571,0.0001020903,0.0001577177,0.0001402139,0.0002311917,0.0005358686,0.0007016865],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001412914,"about_ca_system_score_gemma":0.0001717252,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003295163,"about_ca_topic_score_gemma":0.0008709469,"domain_scores_codex":[0.999931,0.000007049882,0.000004655379,0.00001220903,0.00001219603,0.00003295469],"domain_scores_gemma":[0.9999647,0.000006850371,0.000009840714,0.000004895683,0.000004725947,0.00000885919],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001144824,0.00003852641,0.0002486526,0.0002503575,0.0000100498,0.0004674555,0.0001016776,0.0002598825,0.9851791,0.0008591077,0.0003854228,0.01208518],"study_design_scores_gemma":[0.00001927285,0.0001796159,0.001336431,0.000008253954,0.00001162115,0.0005181985,0.00001989435,0.000322963,0.992035,0.00008107925,0.00545774,0.00001003159],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9525806,0.005049318,0.01987249,0.0002442933,0.0001131448,0.00005492897,0.000407743,0.0005153084,0.0211621],"genre_scores_gemma":[0.9902821,0.002053659,0.00330818,0.00006068911,0.00002027175,0.00002096857,0.0001665457,0.00003269267,0.004054978],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001436369,"threshold_uncertainty_score":0.004805207,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01256313739271087,"score_gpt":0.2256280769949734,"score_spread":0.2130649396022626,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}