{"id":"W2949515170","doi":"10.1021/ic900651n","title":"On the Reactivity of F<sub>3</sub>S≡NXeF<sup>+</sup>: Syntheses and Structural Characterizations of [F<sub>4</sub>S═N−Xe---N≡SF<sub>3</sub>][AsF<sub>6</sub>], a Rare Example of a N−Xe−N Linkage, and [F<sub>3</sub>S(N≡SF<sub>3</sub>)<sub>2</sub>][AsF<sub>6</sub>]","year":2009,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Triple bond; Chemistry; Crystallography; Bond length; Van der Waals radius; Single bond; Raman spectroscopy; Nuclear magnetic resonance spectroscopy; Bond order; Bond energy; van der Waals force; Stereochemistry; Crystal structure; Double bond; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.003134758,0.007266822,0.007760153,0.001644129,0.003176497,0.001432446,0.00522083,0.006839224,0.0002067015],"category_scores_gemma":[0.004263831,0.007240029,0.003106007,0.005815901,0.004391942,0.002732211,0.003167523,0.009073351,0.0002947956],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.002613922,"about_ca_system_score_gemma":0.003226678,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000216824,"about_ca_topic_score_gemma":0.0002533261,"domain_scores_codex":[0.9698269,0.001394134,0.008581158,0.007838224,0.00561383,0.00674572],"domain_scores_gemma":[0.9730459,0.005064435,0.007296262,0.008344626,0.003114132,0.003134688],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002219837,0.002800783,0.001584906,0.004251932,0.003075026,0.0006340431,0.003154016,0.0003582441,0.9521707,0.0003664907,0.00237837,0.02700562],"study_design_scores_gemma":[0.007562635,0.001010776,0.005256882,0.00456922,0.003073265,0.002270856,0.001889527,0.002393484,0.9624845,0.002259492,0.0003528157,0.006876486],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9825566,0.003624471,0.0002999865,0.001378437,0.001392096,0.003476543,0.004334639,0.00170418,0.001233076],"genre_scores_gemma":[0.9809734,0.01000521,0.0001278503,0.000927695,0.00290777,0.0005499107,0.002779843,0.001674227,0.00005414509],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02012914,"threshold_uncertainty_score":0.9996042,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01033254501827412,"score_gpt":0.1992947045386963,"score_spread":0.1889621595204222,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}