{"id":"W2949536029","doi":"10.1002/chin.201151106","title":"ChemInform Abstract: Nucleophilic Ring Opening of Cyclopropane Hemimalonates Using Internal Broensted Acid Activation.","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Cyclopropane; Ring (chemistry); Nucleophile; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002147132,0.0005765169,0.0001589941,0.0002915807,0.0002333151,0.0002729584,0.0003978515,0.000327654,0.009337002],"category_scores_gemma":[0.0001921135,0.0001403088,0.0001667801,0.0002040245,0.0002416276,0.0005006906,0.0003692424,0.0005652864,0.002135077],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002584575,"about_ca_system_score_gemma":0.000353713,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002960666,"about_ca_topic_score_gemma":0.0007402478,"domain_scores_codex":[0.9998814,0.0000147399,0.000005380511,0.00002454969,0.00002798979,0.00004590901],"domain_scores_gemma":[0.9999492,0.0000112924,0.0000140144,0.000007123026,0.000006668301,0.00001162112],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008331914,0.0001867947,0.0005050394,0.0008760234,0.00005426641,0.0006933254,0.0001677795,0.001310219,0.9165676,0.01786368,0.004142381,0.05679954],"study_design_scores_gemma":[0.00004008376,0.0003809544,0.0005352159,0.00002722953,0.00001884901,0.0003263546,0.00001648799,0.000661265,0.9853785,0.0003416956,0.01225991,0.00001361333],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7814732,0.00721943,0.03426987,0.00079052,0.0004550756,0.000340923,0.001422982,0.0009359473,0.173092],"genre_scores_gemma":[0.9782023,0.002242954,0.004870758,0.00009348858,0.00003392144,0.00004287099,0.0006337018,0.00004055121,0.01383943],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009337002,"threshold_uncertainty_score":0.0312354,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03621422659611691,"score_gpt":0.2455273874815396,"score_spread":0.2093131608854227,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}