{"id":"W2949542989","doi":"10.1002/chin.201147031","title":"ChemInform Abstract: Substituent‐Controlled Reactivity in the Nazarov Cyclization of Allenyl Vinyl Ketones.","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"","keywords":"Chemistry; Substituent; Ketone; Reactivity (psychology); Alkyl; Methyl vinyl ketone; Medicinal chemistry; Substitution (logic); Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002924122,0.0004076914,0.0003424193,0.0002101917,0.0002653077,0.000397885,0.0004491118,0.0002719637,0.006258282],"category_scores_gemma":[0.0003255926,0.0001211945,0.0001999891,0.000226846,0.0002192586,0.0004584484,0.0002536923,0.0003258279,0.0006094521],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004244363,"about_ca_system_score_gemma":0.000435787,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00169029,"about_ca_topic_score_gemma":0.003334734,"domain_scores_codex":[0.9999243,0.00002286928,0.000002053627,0.000009351565,0.00002107526,0.00002036448],"domain_scores_gemma":[0.9998977,0.00005426124,0.00001576743,0.00001274226,0.00001121721,0.000008269571],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002818285,0.0004672458,0.006374016,0.002215944,0.0002526419,0.0007951834,0.0002611782,0.6703547,0.0781637,0.1422963,0.01186435,0.08413639],"study_design_scores_gemma":[0.001130074,0.002338142,0.004526135,0.000148255,0.0002538502,0.0003634614,0.0002620587,0.819146,0.1196286,0.02374415,0.02833396,0.000125403],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9420267,0.001558128,0.01077483,0.0002362029,0.00008035662,0.00005391525,0.0008944912,0.0003043193,0.04407107],"genre_scores_gemma":[0.9947799,0.0004768733,0.002763475,0.000034668,0.00001170773,0.00003141764,0.0003373328,0.00004259863,0.001521919],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006258282,"threshold_uncertainty_score":0.02093601,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02394381452978903,"score_gpt":0.2286121593893683,"score_spread":0.2046683448595793,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}