{"id":"W2949546168","doi":"10.1002/chin.200217043","title":"ChemInform Abstract: Catalytic Asymmetric Cyclopropanation of Allylic Alcohols with Titanium‐TADDOLate: Scope of the Cyclopropanation Reaction.","year":2002,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Cyclopropanation; Chemistry; Allylic rearrangement; Scope (computer science); Catalysis; Combinatorial chemistry; Organic chemistry; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002109947,0.001000751,0.000288258,0.0005962259,0.0003672883,0.0005161926,0.0009692227,0.0005222911,0.01446974],"category_scores_gemma":[0.0001784369,0.0002646978,0.0003536626,0.0004571616,0.0003112775,0.0007859119,0.0004310624,0.000820376,0.00469383],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004844871,"about_ca_system_score_gemma":0.0006374725,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006928315,"about_ca_topic_score_gemma":0.0008028421,"domain_scores_codex":[0.9998512,0.00001222214,0.000009029503,0.0000311518,0.00004214227,0.00005413193],"domain_scores_gemma":[0.9999663,0.000005753699,0.000007526966,0.000004503254,0.000007066784,0.00000897804],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001315479,0.0003363082,0.0003940753,0.00250726,0.00009215407,0.001665356,0.0002314059,0.001619388,0.8378923,0.02654076,0.02719083,0.1002147],"study_design_scores_gemma":[0.0001576739,0.0005503665,0.0005228681,0.00007295857,0.00006007775,0.001061012,0.00004358591,0.00116941,0.9475223,0.001894152,0.04691244,0.00003317774],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.416353,0.04678139,0.07851277,0.003377874,0.004085844,0.001024237,0.004419908,0.002529167,0.4429158],"genre_scores_gemma":[0.9107577,0.0268572,0.009245702,0.0004869135,0.0003131253,0.000165915,0.001975811,0.000183244,0.05001443],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.01446974,"threshold_uncertainty_score":0.04840612,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01540312973297781,"score_gpt":0.2172719665094292,"score_spread":0.2018688367764514,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}