{"id":"W2949547541","doi":"10.1002/chin.201316040","title":"ChemInform Abstract: Taking the F Out of FLP: Simple Lewis Acid—Base Pairs for Mild Reductions with Neutral Boranes via Borenium Ion Catalysis.","year":2013,"lang":"en","type":"article","venue":"ChemInform","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; DABCO; Boranes; Lewis acids and bases; Catalysis; Base (topology); Stereochemistry; Ion; Medicinal chemistry; Computational chemistry; Combinatorial chemistry; Organic chemistry; Boron","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001944396,0.0008285705,0.0001899482,0.0003289162,0.0003504445,0.0003286823,0.0006897239,0.0004249676,0.02045277],"category_scores_gemma":[0.0001497911,0.0002747445,0.0001331603,0.0002434045,0.0002165436,0.0005969651,0.0005352902,0.0008108137,0.006824424],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004308279,"about_ca_system_score_gemma":0.0004823504,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001036576,"about_ca_topic_score_gemma":0.00175767,"domain_scores_codex":[0.9998747,0.00001182893,0.000005332117,0.00002572371,0.00005504502,0.00002730167],"domain_scores_gemma":[0.9999614,0.000004950778,0.000006307076,0.000006895982,0.0000075957,0.0000127805],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007567329,0.0001586816,0.0001988749,0.0006699258,0.000034209,0.0002865673,0.0001516571,0.0005780808,0.8872618,0.01206397,0.03439654,0.06344297],"study_design_scores_gemma":[0.0001574463,0.0002570742,0.0004538943,0.00002985145,0.00001939748,0.0003001935,0.00002962174,0.0008695829,0.9121199,0.0009584551,0.08476713,0.00003748837],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.4088564,0.008250317,0.1207214,0.003608264,0.001537261,0.0008470461,0.01236303,0.009919462,0.4338968],"genre_scores_gemma":[0.8870635,0.005827865,0.03925317,0.0006306682,0.0001695267,0.000317391,0.007063651,0.0007580782,0.05891616],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.02045277,"threshold_uncertainty_score":0.0684213,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01627989954933235,"score_gpt":0.2369515569726949,"score_spread":0.2206716574233625,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}