{"id":"W2949559594","doi":"10.1002/chin.200624065","title":"Acyclic Diaminocarbenes: Simple, Versatile Ligands for Cross‐Coupling Reactions.","year":2006,"lang":"en","type":"article","venue":"ChemInform","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Simple (philosophy); Coupling reaction; Combinatorial chemistry; Coupling (piping); Service (business); Computational chemistry; Organic chemistry; Catalysis; Epistemology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002874495,0.0006359436,0.0002398816,0.0003495724,0.0002272593,0.0004124345,0.0007719208,0.0003546814,0.008358849],"category_scores_gemma":[0.0003537539,0.0002581304,0.0001219879,0.0004714325,0.0002368355,0.0006481428,0.0005178864,0.0007764602,0.003079577],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004743377,"about_ca_system_score_gemma":0.00024799,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004854329,"about_ca_topic_score_gemma":0.00118928,"domain_scores_codex":[0.9997682,0.00005652025,0.00001258134,0.00005520901,0.00005499529,0.00005245446],"domain_scores_gemma":[0.9999121,0.00001963094,0.00002085235,0.00001218824,0.000009824003,0.00002534638],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007296914,0.000169809,0.0002053133,0.0009830081,0.0000374061,0.0005069932,0.0001921301,0.001360542,0.8902613,0.01591134,0.01400269,0.07563982],"study_design_scores_gemma":[0.0001198719,0.0007314,0.0005530408,0.00005980142,0.00003334938,0.0008417872,0.00005817862,0.001269253,0.8793738,0.001525264,0.115383,0.00005130965],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5319362,0.06870791,0.1511254,0.002075152,0.001452189,0.0007431496,0.006222838,0.004949445,0.2327877],"genre_scores_gemma":[0.918664,0.02175531,0.0229739,0.0005195475,0.0001446702,0.0002713369,0.002177684,0.0002507492,0.03324278],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008358849,"threshold_uncertainty_score":0.0279631,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009951769053129552,"score_gpt":0.2530667945177062,"score_spread":0.2431150254645766,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}