{"id":"W2949566538","doi":"10.1055/s-0032-1317342","title":"Silver-Catalyzed Direct Addition of Terminal Alkynes to Simple Cyclic Ketones in Water","year":2012,"lang":"en","type":"article","venue":"Synlett","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Fonds Québécois de la Recherche sur la Nature et les Technologies; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Chemistry; Propargyl; Catalysis; Terminal (telecommunication); Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000132413,0.0005782009,0.0002099776,0.0001783323,0.000124137,0.0001840541,0.0003132289,0.0002503929,0.001262351],"category_scores_gemma":[0.0001611515,0.000203998,0.0001725364,0.0001432705,0.0002532573,0.0003604284,0.0003328085,0.0005068808,0.0004863796],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001865,"about_ca_system_score_gemma":0.0001963129,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005256164,"about_ca_topic_score_gemma":0.001526768,"domain_scores_codex":[0.9999013,0.000008218568,0.000007511454,0.0000202314,0.00002564488,0.00003710677],"domain_scores_gemma":[0.9999578,0.000007439864,0.000008141557,0.000004143385,0.000009627486,0.00001285279],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006368224,0.00001625909,0.00007287549,0.0001177647,0.000006513782,0.0002247559,0.00007726095,0.0001100614,0.9941796,0.0004951471,0.0001943437,0.004441764],"study_design_scores_gemma":[0.0000149039,0.0001368801,0.000266599,0.000005986237,0.000006488809,0.0001028232,0.00001964913,0.0002548726,0.9970131,0.0001002149,0.002071395,0.000007007931],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9609562,0.002341151,0.02209441,0.0002218471,0.0002693999,0.0001476113,0.0002699801,0.0003922576,0.0133072],"genre_scores_gemma":[0.9882945,0.001496822,0.004906497,0.00003757178,0.00001382676,0.00003483488,0.0001619634,0.00003582715,0.005018133],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001262351,"threshold_uncertainty_score":0.004222929,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01229869754861469,"score_gpt":0.2563605137269137,"score_spread":0.244061816178299,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}