{"id":"W2949588925","doi":"10.1002/chin.201611155","title":"ChemInform Abstract: Gold‐Catalyzed Tandem Reactions of Amide—Aldehyde—Alkyne Coupling and Cyclization‐Synthesis of 2,4,5‐Trisubstituted Oxazoles.","year":2016,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Alkyne; Tandem; Amide; Aldehyde; Catalysis; Coupling (piping); Combinatorial chemistry; Coupling reaction; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002295341,0.0003346389,0.0005741742,0.0001807804,0.000093716,0.00002391448,0.0003194682,0.0003293241,0.001406247],"category_scores_gemma":[0.001092361,0.0002826768,0.0001957666,0.0003603224,0.0004575683,0.0006432078,0.0001374259,0.000190573,0.00003457848],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002930819,"about_ca_system_score_gemma":0.0002023369,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001356629,"about_ca_topic_score_gemma":0.00002069649,"domain_scores_codex":[0.9977019,5.857379e-8,0.001160079,0.0003279278,0.0004266993,0.000383324],"domain_scores_gemma":[0.9971159,0.0006940271,0.0009223199,0.0007448664,0.000318248,0.0002046614],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005973876,0.0001452129,0.0005756575,0.000775965,0.0002234068,0.000002525999,0.0002335261,0.000002385072,0.8641622,0.0005148331,0.001675505,0.1316291],"study_design_scores_gemma":[0.0008961834,0.000004547477,0.001157263,0.0007147538,0.0001547336,0.00004545681,0.0004853863,0.00004435557,0.987323,0.00009451524,0.008748981,0.0003307664],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.3895568,0.0002089904,0.00001466133,0.000151014,0.00009209605,0.0001916441,0.0002731175,0.0002016215,0.6093101],"genre_scores_gemma":[0.9884124,0.0006261681,0.00006056487,0.000005886875,0.0001086397,0.00005348129,0.0001278528,0.00004511477,0.01055992],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.5988556,"threshold_uncertainty_score":0.9999626,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01442537144609066,"score_gpt":0.2379999569547162,"score_spread":0.2235745855086256,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}