{"id":"W2949593857","doi":"10.1002/chin.200238035","title":"Increased Felkin—Anh Selectivity in Nucleophilic Additions to α‐Chiral Aldehydes Using Vinylalanes.","year":2002,"lang":"en","type":"article","venue":"ChemInform","topic":"Axial and Atropisomeric Chirality Synthesis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Selectivity; Nucleophile; Medicinal chemistry; Nucleophilic addition; Organic chemistry; Computational chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006713752,0.0002465736,0.0003125613,0.00008959806,0.0001352457,0.00004760664,0.0002500358,0.0001443894,0.007102584],"category_scores_gemma":[0.0002066756,0.0002505984,0.0001267156,0.0004190288,0.00007040899,0.0002209194,0.0001016075,0.0002261253,0.0002108084],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002793819,"about_ca_system_score_gemma":0.0000305285,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006343188,"about_ca_topic_score_gemma":0.0001121387,"domain_scores_codex":[0.9986696,0.000001160827,0.0003374703,0.0003032252,0.0002254849,0.0004630402],"domain_scores_gemma":[0.9992245,0.0000979878,0.00009034669,0.0003479494,0.00003346553,0.0002057577],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001816143,0.001532795,0.02015081,0.0007986166,0.0002104016,0.0001111791,0.006303245,0.00004055433,0.3402854,0.0004190262,0.0289318,0.6010346],"study_design_scores_gemma":[0.001895686,0.0000696604,0.0103863,0.0004365809,0.00009748906,0.0001203155,0.000949897,0.00419363,0.8943452,0.001016302,0.08466303,0.001825934],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.787513,0.00003381104,0.000001863597,0.0002275644,0.00003275898,0.00008214773,0.00008168819,0.0001253219,0.2119018],"genre_scores_gemma":[0.9944295,0.00001057057,0.0002541969,0.0002596559,0.0003085699,0.00003219316,0.0000407696,0.00002732509,0.004637188],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5992087,"threshold_uncertainty_score":0.9999946,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02486400002658142,"score_gpt":0.2284993980035016,"score_spread":0.2036353979769202,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}