{"id":"W2949623001","doi":"10.1002/chin.201328249","title":"ChemInform Abstract: In situ Spectroscopic Detection of Active Surface Species in Asymmetric Heterogeneous Catalysis","year":2013,"lang":"en","type":"article","venue":"ChemInform","topic":"Surface Chemistry and Catalysis","field":"Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemistry; In situ; Catalysis; Nanotechnology; Surface (topology); Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00008795389,0.000240523,0.0003730095,0.0002161685,0.00001767294,0.00002758129,0.000216115,0.0001862051,0.0005599214],"category_scores_gemma":[0.00005948086,0.0002591378,0.0001154823,0.001097244,0.0000490923,0.0004364006,0.00004260604,0.0002636662,0.00009764748],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004392882,"about_ca_system_score_gemma":0.00001961643,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002204214,"about_ca_topic_score_gemma":0.000179827,"domain_scores_codex":[0.9987419,7.793007e-8,0.0005010455,0.0001806718,0.0002071227,0.0003692157],"domain_scores_gemma":[0.9993805,0.00007077708,0.00009811956,0.0003225213,0.00004890405,0.00007923664],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001218888,0.00004796797,0.000558282,0.0002609602,0.00006034306,0.000004776115,0.0008457042,0.0006907942,0.875523,5.183088e-7,0.0001168359,0.1218786],"study_design_scores_gemma":[0.0003236733,0.000009953264,0.0155472,0.00003098693,0.0000143949,0.000004579087,0.0007108165,0.0001259293,0.9828039,0.00001284819,0.0001806319,0.0002351268],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7116904,0.0002035453,5.008185e-7,0.000004435145,0.00004317719,0.0001184811,0.000004484466,0.00005296851,0.287882],"genre_scores_gemma":[0.9975576,0.0001217759,0.00001123643,0.000004479869,0.00002504317,0.00003070109,0.00005770903,0.00002100817,0.002170392],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2858673,"threshold_uncertainty_score":0.9999861,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007016634832177848,"score_gpt":0.1954443052236173,"score_spread":0.1884276703914395,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}