{"id":"W2949642776","doi":"10.1139/v06-137","title":"Ruthenium(III) acetylacetonate [Ru(acac)<sub>3</sub>] — An efficient chemoselective catalyst for the tetrahydropyranylation (THP) of alcohols and phenols under solvent-free conditions","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Ruthenium; Catalysis; Phenols; Solvent; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000102048,0.0003001713,0.0001940802,0.0001413778,0.0001059134,0.0001799926,0.0002608412,0.0002054004,0.001020434],"category_scores_gemma":[0.0001281621,0.0001247076,0.0001239751,0.0001724243,0.0002338788,0.000196684,0.000166407,0.0003239379,0.0008478582],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002252842,"about_ca_system_score_gemma":0.0001842169,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00126568,"about_ca_topic_score_gemma":0.002212908,"domain_scores_codex":[0.9998847,0.00001577681,0.000007324075,0.00002192821,0.00004067284,0.00002969622],"domain_scores_gemma":[0.9999373,0.000009965883,0.00002045809,0.000009546513,0.00001317632,0.000009435985],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003291261,0.000004936578,0.00003712068,0.00002981249,0.000003839324,0.00002756944,0.000006999911,0.00004179828,0.9971903,0.0001072973,0.00008385882,0.002433585],"study_design_scores_gemma":[0.000004536328,0.00005999148,0.0003509348,0.000001509145,0.000008027452,0.0001212689,0.000004947268,0.0002485976,0.9968482,0.00002212717,0.00232735,0.000002516971],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9539987,0.005440519,0.02697958,0.0002284509,0.0001065611,0.00008475616,0.0004430398,0.0006458922,0.01207246],"genre_scores_gemma":[0.9886129,0.0009593369,0.007535806,0.00002962403,0.00001504171,0.000008555587,0.0002073195,0.00003617369,0.002595271],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00126568,"threshold_uncertainty_score":0.003413677,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009013997685742917,"score_gpt":0.2144209834882874,"score_spread":0.2054069858025445,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}