{"id":"W2949660353","doi":"10.1021/ol0498141","title":"Enantioselective Total Synthesis of (−)-Dehydrobatzelladine C","year":2004,"lang":"en","type":"article","venue":"Organic Letters","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Heart, Lung, and Blood Institute; Natural Sciences and Engineering Research Council of Canada; Cytokinetics","keywords":"Enantioselective synthesis; Chemistry; Total synthesis; Combinatorial chemistry; Catalysis; Stereochemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000149731,0.0004911328,0.0003214889,0.000212388,0.0002373692,0.0001889086,0.0003637062,0.000274771,0.002013925],"category_scores_gemma":[0.0001501426,0.0001377741,0.0001849198,0.0002136743,0.0001718791,0.0002158169,0.0003532439,0.0004716786,0.0006211477],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002245902,"about_ca_system_score_gemma":0.00042072,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007360795,"about_ca_topic_score_gemma":0.001156962,"domain_scores_codex":[0.9999059,0.00001216357,0.000007396347,0.00002104591,0.00002057482,0.00003285449],"domain_scores_gemma":[0.9999232,0.000007628673,0.00001318321,0.00001555224,0.00001864972,0.00002171584],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001382857,0.00003696927,0.0001711961,0.0001937332,0.00002333616,0.0003505074,0.0001153231,0.0004790198,0.987852,0.001082731,0.0001949282,0.009362088],"study_design_scores_gemma":[0.00004459542,0.0005458284,0.0008912235,0.000009509239,0.0000253654,0.000587335,0.00004451613,0.0004151931,0.9876205,0.0002215897,0.009576281,0.00001793021],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9510774,0.001741893,0.02234042,0.000149975,0.0001133844,0.0002016013,0.001371221,0.0002753779,0.02272889],"genre_scores_gemma":[0.9833084,0.001029514,0.01003941,0.00004680749,0.000009064073,0.00004545226,0.0005203596,0.00003575088,0.004965273],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002013925,"threshold_uncertainty_score":0.006737232,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00280116057406416,"score_gpt":0.1846476826861796,"score_spread":0.1818465221121154,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}