{"id":"W2949696650","doi":"10.1021/jo001402s","title":"Selective<i>Ortho</i>and Benzylic Functionalization of Secondary and Tertiary<i>p</i>-Tolylsulfonamides.<i>Ipso</i>-Bromo Desilylation and Suzuki Cross-Coupling Reactions","year":2001,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Chemical synthesis and alkaloids","field":"Chemistry","cited_by":62,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University; University of Waterloo","funders":"","keywords":"Chemistry; Suzuki reaction; Surface modification; Tertiary alcohols; Coupling reaction; Coupling (piping); Medicinal chemistry; Organic chemistry; Combinatorial chemistry; Stereochemistry; Palladium; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002208511,0.0004026831,0.0002174399,0.0001405696,0.0001353888,0.0001657858,0.0002653125,0.0001556271,0.001873078],"category_scores_gemma":[0.000236663,0.0001515581,0.0001679798,0.0001129839,0.0002131422,0.000248388,0.0002236141,0.000291584,0.0005770882],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002463578,"about_ca_system_score_gemma":0.000265557,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004536391,"about_ca_topic_score_gemma":0.001572835,"domain_scores_codex":[0.9998676,0.00002352087,0.00001257434,0.00002042605,0.00003410703,0.00004183367],"domain_scores_gemma":[0.9998931,0.00001677964,0.0000368395,0.00001228121,0.00001596395,0.00002505539],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000121548,0.00001781013,0.00009687242,0.00008360646,0.000005191186,0.00006573046,0.00004150457,0.0001199291,0.9967175,0.0003402247,0.00008421391,0.002305827],"study_design_scores_gemma":[0.0000111188,0.0002048068,0.0005746949,0.000002781266,0.000006157434,0.0001253568,0.00001250363,0.0002480222,0.9971147,0.00003122607,0.001664458,0.00000417324],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9721909,0.00181266,0.01009468,0.0001316529,0.00004301294,0.00007881776,0.0005233304,0.0001765326,0.01494852],"genre_scores_gemma":[0.9913369,0.001034146,0.003967514,0.00003285102,0.00001130351,0.00002942983,0.0002940572,0.00003506136,0.003258656],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001873078,"threshold_uncertainty_score":0.006266057,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007806202489651979,"score_gpt":0.2204940552836491,"score_spread":0.2126878527939971,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}