{"id":"W2949729583","doi":"10.1021/om700312c","title":"A Highly Active Chiral Ruthenium-Based Catalyst for Enantioselective Olefin Metathesis","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":85,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Desymmetrization; Chemistry; Enantioselective synthesis; Catalysis; Ruthenium; Metathesis; Olefin metathesis; Denticity; Reactivity (psychology); Olefin fiber; Ligand (biochemistry); Ring-opening metathesis polymerisation; Combinatorial chemistry; Organic chemistry; Medicinal chemistry; Metal; Polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001628918,0.0004875498,0.0004090352,0.0003546219,0.000184079,0.0004973412,0.0008043683,0.0005143674,0.0008570338],"category_scores_gemma":[0.0002239905,0.0001928859,0.0002197584,0.0002143622,0.0001904974,0.0004308831,0.0003693318,0.0006214073,0.0008698252],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004477542,"about_ca_system_score_gemma":0.0002840899,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000425839,"about_ca_topic_score_gemma":0.0006263055,"domain_scores_codex":[0.9998156,0.00001651362,0.00001495071,0.00002606151,0.00008151801,0.00004540255],"domain_scores_gemma":[0.9999479,0.000007892759,0.00001098464,0.000008895402,0.000008747009,0.00001563091],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008357081,0.0001107308,0.000187335,0.0001378569,0.00001606011,0.0004500633,0.00001633372,0.001037398,0.9757915,0.001757164,0.0005546442,0.01985746],"study_design_scores_gemma":[0.00003201788,0.000141709,0.00031171,0.000008906371,0.00002555891,0.0005038914,0.000006667155,0.003613243,0.989363,0.0002005797,0.005779202,0.00001354996],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9026259,0.009330024,0.05944442,0.0008878932,0.000404457,0.0002404047,0.0008100593,0.001932032,0.02432485],"genre_scores_gemma":[0.9840044,0.002093014,0.009903344,0.00006705521,0.00004613677,0.00003210699,0.0003645093,0.00007512614,0.003414367],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008570338,"threshold_uncertainty_score":0.003248692,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0181242484841259,"score_gpt":0.2743287136298165,"score_spread":0.2562044651456906,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}