{"id":"W2949729583","doi":"10.1021/om700312c","title":"A Highly Active Chiral Ruthenium-Based Catalyst for Enantioselective Olefin Metathesis","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":85,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Desymmetrization; Chemistry; Enantioselective synthesis; Catalysis; Ruthenium; Metathesis; Olefin metathesis; Denticity; Reactivity (psychology); Olefin fiber; Ligand (biochemistry); Ring-opening metathesis polymerisation; Combinatorial chemistry; Organic chemistry; Medicinal chemistry; Metal; Polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0009150793,0.0004918668,0.0006337946,0.0001528759,0.0002155904,0.00006154739,0.0005879549,0.0003544519,0.001904532],"category_scores_gemma":[0.001449648,0.000477908,0.0004166249,0.0006766884,0.0001839453,0.0001160835,0.00008381403,0.0003271439,0.0000677572],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004265063,"about_ca_system_score_gemma":0.0002814022,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000236031,"about_ca_topic_score_gemma":0.00001994297,"domain_scores_codex":[0.9973351,0.00003535059,0.0005847497,0.0007873788,0.0004190362,0.0008383812],"domain_scores_gemma":[0.9969197,0.001415506,0.0003403325,0.0008287411,0.0002251437,0.0002706101],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002676066,0.0003272413,0.0001153264,0.0001563756,0.0003643033,0.00001066196,0.0004203671,0.000003029972,0.9806591,0.0005459925,0.00006206461,0.01706798],"study_design_scores_gemma":[0.001257067,0.00003724705,0.0001829277,0.00002766921,0.0003905936,0.00002229425,0.0003998412,0.000103182,0.9812693,0.000874675,0.01487661,0.0005586211],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8766361,0.0002840599,0.07899088,0.0005691394,0.0003300232,0.0005246727,0.0005164732,0.0006005756,0.04154808],"genre_scores_gemma":[0.9498545,0.000008014877,0.04354126,0.0001269974,0.0004406007,0.00007142732,0.0001716163,0.0001816009,0.005603977],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07321842,"threshold_uncertainty_score":0.9997672,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0181242484841259,"score_gpt":0.2743287136298165,"score_spread":0.2562044651456906,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}