{"id":"W2949738588","doi":"10.1002/jhet.5570400214","title":"Efficient synthesis of bromocyclopenta[<i>b</i>] indoles via a bromination ‐ reduction sequence","year":2003,"lang":"en","type":"article","venue":"Journal of Heterocyclic Chemistry","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"Merck Canada Inc. (Canada)","funders":"","keywords":"Chemistry; Bromine; Halogenation; Pyridine; Adduct; Sequence (biology); Medicinal chemistry; Stereochemistry; Double bond; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003507421,0.0002227574,0.0005195901,0.0001149468,0.00007190418,0.00002720786,0.0003381808,0.0001835308,0.0005381142],"category_scores_gemma":[0.0006726331,0.0002027693,0.0003997732,0.0003062511,0.0001090081,0.00008993496,0.00003439508,0.0002747168,0.000005573651],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002515763,"about_ca_system_score_gemma":0.00005161599,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001074054,"about_ca_topic_score_gemma":2.157559e-7,"domain_scores_codex":[0.9978685,0.00004173184,0.0009872997,0.0002411369,0.0006220015,0.000239281],"domain_scores_gemma":[0.997737,0.0002020083,0.001333828,0.0003633803,0.0002187477,0.000145069],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005240131,0.0002992611,0.0004687686,0.0002378218,0.0001399266,0.00001615469,0.00009086885,0.000218692,0.971419,0.000002771286,0.00005451892,0.0269998],"study_design_scores_gemma":[0.0003916869,0.00001011175,0.0001043284,0.0002571706,0.0001835874,0.001093761,0.0005345105,0.0001293982,0.9966549,0.00004752808,0.0004077666,0.0001852378],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9878135,0.0006052908,0.0004778088,0.00003910795,0.00009237554,0.00002897463,0.00001049505,0.00001281949,0.01091965],"genre_scores_gemma":[0.9988266,0.0001075297,0.0007198326,0.00000482633,0.0001443151,0.000006489124,0.000003071752,0.00002462375,0.0001627676],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02681456,"threshold_uncertainty_score":0.826869,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01133084688955594,"score_gpt":0.2348014724184866,"score_spread":0.2234706255289307,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}