{"id":"W2949746627","doi":"10.1002/chin.200715086","title":"Curtius Rearrangement of Aromatic Carboxylic Acids to Access Protected Anilines and Aromatic Ureas.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Curtius rearrangement; Aromaticity; Organic chemistry; Combinatorial chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002456192,0.0001699587,0.0002687594,0.0001913092,0.00004477896,0.00003500647,0.0002709291,0.0001069366,0.0003162271],"category_scores_gemma":[0.000321801,0.0001526422,0.00006713566,0.0007236457,0.00004483272,0.0001380792,0.000118468,0.00008933783,0.00001694378],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008078483,"about_ca_system_score_gemma":0.00003393541,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004662512,"about_ca_topic_score_gemma":0.0000154062,"domain_scores_codex":[0.9987134,3.942316e-7,0.000493646,0.0001890617,0.0003524222,0.0002510401],"domain_scores_gemma":[0.9991459,0.00005748991,0.0001916852,0.0003547136,0.00006196481,0.0001882786],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000107056,0.0002354618,0.003999039,0.001784626,0.0003549635,0.00001347431,0.003765093,0.000003183635,0.2875165,0.00003646689,0.001720155,0.700464],"study_design_scores_gemma":[0.0004855868,0.0000189683,0.002569867,0.00009004876,0.0000719243,0.00001121517,0.0005979417,0.0001178906,0.993096,0.00007459464,0.002657608,0.0002083519],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7991205,0.0001095617,0.00003929439,0.00006514368,0.00001937343,0.0001867755,0.000006341776,0.00007328655,0.2003797],"genre_scores_gemma":[0.9973503,0.00001140609,0.0002602942,0.00007665643,0.00005361428,0.00004943453,0.00004528439,0.00001637198,0.002136584],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.7055795,"threshold_uncertainty_score":0.6224566,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01509713886355076,"score_gpt":0.2712384523782841,"score_spread":0.2561413135147333,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}