{"id":"W2949759525","doi":"10.1021/jo0104431","title":"Stereoselective Reactions of Acyclic Allylic Phosphates with Organocopper Reagents","year":2001,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Stereoselectivity; Regioselectivity; Chemistry; Allylic rearrangement; Reagent; Kinetic resolution; Stereochemistry; Medicinal chemistry; Organic chemistry; Enantioselective synthesis; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003264154,0.0001868939,0.0003607346,0.00003973641,0.00009959457,0.00001770974,0.0005398371,0.000104762,0.004846398],"category_scores_gemma":[0.0002627206,0.00011523,0.0001334435,0.0006285249,0.0001082363,0.0001137639,0.00005791647,0.0003542738,0.00001231197],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001327318,"about_ca_system_score_gemma":0.0001548592,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000212375,"about_ca_topic_score_gemma":0.000003597208,"domain_scores_codex":[0.998646,0.00002073338,0.0005530181,0.0001302054,0.0004339306,0.0002161756],"domain_scores_gemma":[0.9979742,0.0002793695,0.0008990404,0.0004421675,0.0002981934,0.0001070692],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002212226,0.0002030642,0.005780514,0.00005510741,0.0005745142,0.00001502919,0.0003298002,0.000004904336,0.9881496,6.871649e-7,0.0003176888,0.004347797],"study_design_scores_gemma":[0.0005668351,0.00003128358,0.0009679288,0.0001162785,0.0004369607,0.001182716,0.001928711,0.000003605414,0.9919222,0.0000300603,0.002678998,0.0001344197],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9819084,0.0009225608,0.0001914218,0.0002336173,0.00002233195,0.00002709492,0.000004835137,0.00001516696,0.01667456],"genre_scores_gemma":[0.995588,0.000915678,0.0001215433,0.00002388408,0.0001867382,0.000001187893,0.000003135609,0.00003634323,0.003123474],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0136796,"threshold_uncertainty_score":0.9960633,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0078423704511878,"score_gpt":0.2085342476661979,"score_spread":0.2006918772150101,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}