{"id":"W2949769122","doi":"10.1002/chin.201244023","title":"ChemInform Abstract: Grob Fragmentation of 2‐Azabicyclo[2.2.2]oct‐7‐ene: Tool for the Stereoselective Synthesis of Polysubstituted Piperidines.","year":2012,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis and Reactivity of Heterocycles","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Stereoselectivity; Fragmentation (computing); Nucleophile; Ene reaction; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002960647,0.0002774395,0.0004396935,0.00006518462,0.0001257479,0.00002221526,0.0003506373,0.000223248,0.0007027708],"category_scores_gemma":[0.000420379,0.0002009305,0.0003233426,0.0001163347,0.000205035,0.0005637266,0.00005958457,0.0001406392,0.000006291028],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001108524,"about_ca_system_score_gemma":0.00006191531,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000108416,"about_ca_topic_score_gemma":0.000005011975,"domain_scores_codex":[0.9984384,1.456193e-7,0.0006230783,0.000172809,0.0003412796,0.0004242787],"domain_scores_gemma":[0.9975557,0.00116085,0.000620303,0.0004358432,0.0001443569,0.00008291216],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002044293,0.0002268145,0.0007181604,0.0007774887,0.0002880652,1.534449e-7,0.001295434,6.876216e-7,0.4363005,0.0001051342,0.001769174,0.558314],"study_design_scores_gemma":[0.0003989142,0.00001077935,0.005744185,0.0001415445,0.0001645597,0.000009086211,0.001366959,0.00001697349,0.9849548,0.00002019143,0.006929971,0.0002420199],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7636117,0.000510941,0.000008452654,0.0001063703,0.0001737666,0.0003466294,0.0001559808,0.0000588017,0.2350273],"genre_scores_gemma":[0.997739,0.00008617589,0.0001452279,0.00002343412,0.000255322,0.0001936667,0.00004002467,0.00003138244,0.001485776],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.558072,"threshold_uncertainty_score":0.8193708,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01732012986683943,"score_gpt":0.2503238386104246,"score_spread":0.2330037087435852,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}