{"id":"W2949770468","doi":"10.1002/chin.200740042","title":"α‐Amino Acid Induced Rate Acceleration in Aqueous Biphasic Lewis Acid Catalyzed Michael Addition Reactions.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Catalysis; Lewis acids and bases; Michael reaction; Aqueous solution; Amino acid; Combinatorial chemistry; Acceleration; Medicinal chemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000510561,0.000276743,0.0003152938,0.0003559288,0.0001274553,0.00007092327,0.0002603915,0.0003529199,0.0007860968],"category_scores_gemma":[0.0005119079,0.000283727,0.0001487432,0.0008579739,0.00004457976,0.0005323949,0.00006163949,0.0003137395,0.0001990103],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004705481,"about_ca_system_score_gemma":0.00008166169,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002092806,"about_ca_topic_score_gemma":0.0001431524,"domain_scores_codex":[0.9982038,0.000001117914,0.0006832142,0.0003607008,0.0002930159,0.0004581755],"domain_scores_gemma":[0.9986971,0.000148313,0.0004039787,0.000506016,0.0001052825,0.0001392906],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000428298,0.00004933203,0.0001500881,0.00004066227,0.00003068672,0.00001047431,0.0002669168,1.265975e-7,0.4302531,0.00001578055,0.0005338941,0.5686061],"study_design_scores_gemma":[0.0006437179,0.000008323907,0.001417138,0.00004635633,0.00004285546,0.00002474143,0.0009124619,0.00003562273,0.9886703,0.00003556122,0.007843913,0.0003189321],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6232193,0.0002907083,0.00006137045,0.00008647268,0.0001139696,0.0001188149,0.00004145185,0.0001474355,0.3759204],"genre_scores_gemma":[0.9953524,0.00007313932,0.00007775674,0.00008148018,0.0002637609,0.00006875589,0.001135296,0.0000328938,0.002914458],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5682872,"threshold_uncertainty_score":0.9999615,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01961289897926061,"score_gpt":0.2448838917102396,"score_spread":0.2252709927309789,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}