{"id":"W2949774563","doi":"10.1002/chin.201309106","title":"ChemInform Abstract: Expeditious Synthesis of Tetrasubstituted Helical Alkenes by a Cascade of Palladium‐Catalyzed C—H Activations.","year":2013,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Norbornene; Palladium; Cascade; Catalysis; Alkyne; Steric effects; Combinatorial chemistry; Cascade reaction; Organic chemistry; Polymerization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001555482,0.0004152758,0.0001319901,0.000319936,0.000185351,0.0002340191,0.0003079691,0.0002018136,0.004594413],"category_scores_gemma":[0.000105216,0.0001539057,0.000147959,0.0001901562,0.0001637129,0.0002948404,0.0002941251,0.0004235681,0.001791185],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002822299,"about_ca_system_score_gemma":0.0003934981,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002915843,"about_ca_topic_score_gemma":0.0007310371,"domain_scores_codex":[0.9999157,0.000008592401,0.000005753617,0.00002181598,0.00002308562,0.00002504903],"domain_scores_gemma":[0.9999592,0.000005658485,0.00001010386,0.000007780246,0.000005529072,0.00001174654],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002424949,0.00009370103,0.0002004149,0.0002095069,0.00002028136,0.0002583581,0.00006519533,0.0009206549,0.9650236,0.004038852,0.001907056,0.02701989],"study_design_scores_gemma":[0.00003189595,0.0002724909,0.0004843073,0.000009798607,0.0000122564,0.0002780477,0.00001283681,0.001171541,0.9819194,0.0002248107,0.01557034,0.00001225388],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7968776,0.004824869,0.0992966,0.0004893559,0.0004067592,0.0004357534,0.002906117,0.002250405,0.09251262],"genre_scores_gemma":[0.9710569,0.001834353,0.01675986,0.00007996841,0.00002978715,0.00006503271,0.0006741353,0.00005765657,0.009442354],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004594413,"threshold_uncertainty_score":0.01536983,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01676030507281746,"score_gpt":0.2575717161683944,"score_spread":0.2408114110955769,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}