{"id":"W2949842977","doi":"10.1002/chin.201521033","title":"ChemInform Abstract: Transfer Hydrogenation of Ketones, Nitriles, and Esters Catalyzed by a Half‐Sandwich Complex of Ruthenium.","year":2015,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"","keywords":"Chemistry; Transfer hydrogenation; Aldimine; Ruthenium; Catalysis; Aryl; Hydrolysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002360566,0.000456374,0.0002062718,0.0001381675,0.0001312508,0.0002216574,0.0005492043,0.0003338534,0.006354776],"category_scores_gemma":[0.0001907273,0.0001701455,0.0001293281,0.00008626044,0.0001821308,0.0004626854,0.0003823329,0.0004592326,0.00190309],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000295624,"about_ca_system_score_gemma":0.0002162237,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000285595,"about_ca_topic_score_gemma":0.0003835926,"domain_scores_codex":[0.9998857,0.00001542985,0.000005134666,0.0000257547,0.00003737482,0.00003054735],"domain_scores_gemma":[0.9999416,0.00001167875,0.00001400543,0.00001098354,0.00000737799,0.00001441213],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0003514012,0.00005464548,0.0001139366,0.0002159208,0.00002970527,0.0001913483,0.00006611636,0.0003893776,0.9787923,0.003461408,0.004113828,0.01221995],"study_design_scores_gemma":[0.0000610452,0.000322496,0.0004089711,0.00001124987,0.0000183006,0.0003668217,0.00002280129,0.001389762,0.9897687,0.0002678675,0.007346461,0.00001547327],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.8961669,0.002391574,0.02951394,0.0009413887,0.0003351962,0.00009905028,0.0007923475,0.001660007,0.06809957],"genre_scores_gemma":[0.9873257,0.0005520436,0.003186778,0.00006883065,0.00002166171,0.00002586013,0.0003933262,0.00006862007,0.008357124],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.006354776,"threshold_uncertainty_score":0.02125883,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02247941326020248,"score_gpt":0.2385966229368816,"score_spread":0.2161172096766792,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}