{"id":"W2949847683","doi":"10.1021/jo051491e","title":"Synthesis of <i>N</i>-Diphenylphosphinoylimines Using the Kresze Reaction","year":2005,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Social Sciences and Humanities Research Council of Canada; Canadian Institutes of Health Research","keywords":"Chemistry; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000798323,0.0002561978,0.0004135377,0.0000231615,0.0001981857,0.00003184572,0.001108477,0.0001576206,0.002975658],"category_scores_gemma":[0.0007120069,0.0001537186,0.0002357627,0.0002561188,0.0002339461,0.0001664816,0.0001415297,0.0005367264,0.000009733401],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002708058,"about_ca_system_score_gemma":0.0002228875,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002133496,"about_ca_topic_score_gemma":0.000003756752,"domain_scores_codex":[0.9980834,0.00004021478,0.0008547636,0.0001400653,0.0006015298,0.0002799899],"domain_scores_gemma":[0.9966557,0.0009698042,0.001260904,0.0007645832,0.000258408,0.00009059731],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001324403,0.0001114153,0.0003109236,0.00008918568,0.0001807988,0.000004315065,0.0003334773,0.00004937655,0.9959488,0.000001567192,0.0004834528,0.002354246],"study_design_scores_gemma":[0.0002438079,0.000007476131,0.00009694929,0.0001738887,0.0004677527,0.001053134,0.001247629,0.0001092078,0.9933732,0.00005389532,0.003011748,0.0001612806],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.993802,0.001770381,0.00006754556,0.001523755,0.00009722585,0.00003269296,0.00001090738,0.00002494628,0.002670566],"genre_scores_gemma":[0.9975514,0.0004327183,0.0005750236,0.00005143223,0.0008979235,9.067768e-7,5.737953e-7,0.00005829869,0.0004317419],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003749401,"threshold_uncertainty_score":0.9979358,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01225359219534992,"score_gpt":0.2211526533590312,"score_spread":0.2088990611636813,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}