{"id":"W2949871813","doi":"10.1002/chin.200716080","title":"Highly Regioselective anti‐Markovnikov Palladium‐Borate‐Catalyzed Methoxycarbonylation Reactions: Unprecedented Results for Aryl Olefins.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Markovnikov's rule; Regioselectivity; Aryl; Catalysis; Palladium; Boron; Combinatorial chemistry; Organic chemistry; Medicinal chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004473544,0.0007977852,0.0003998564,0.0003068951,0.000340628,0.0004628753,0.0008246491,0.0004949725,0.002565828],"category_scores_gemma":[0.0003326721,0.0003973687,0.000307661,0.000351857,0.0004322858,0.0009958597,0.0008200895,0.00123765,0.001157769],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004744984,"about_ca_system_score_gemma":0.0004097563,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005972406,"about_ca_topic_score_gemma":0.001510646,"domain_scores_codex":[0.9997359,0.00004888622,0.00002520078,0.00004447026,0.00005433577,0.00009121693],"domain_scores_gemma":[0.9999315,0.00001462746,0.00002060104,0.00001257414,0.000006778464,0.00001393732],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0006292835,0.000379779,0.0003301576,0.001120689,0.0001724564,0.0008306278,0.0004745694,0.002965603,0.8939853,0.01980372,0.009073232,0.07023454],"study_design_scores_gemma":[0.0001600194,0.0006413067,0.0006241372,0.00003112043,0.00005350176,0.0008568944,0.00006884178,0.002716427,0.9538869,0.002405906,0.0384858,0.00006923531],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.8079975,0.02235662,0.09195827,0.001474458,0.001183189,0.0003326703,0.001738051,0.001381278,0.07157796],"genre_scores_gemma":[0.9644104,0.01083523,0.01383705,0.0002699691,0.0001106071,0.0001018822,0.0006984136,0.0001637347,0.009572852],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.002565828,"threshold_uncertainty_score":0.008583546,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02657277550279974,"score_gpt":0.3028022896113379,"score_spread":0.2762295141085382,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}