{"id":"W2949872754","doi":"10.1002/chin.201143089","title":"ChemInform Abstract: A Stereoselective Oxidative Polycyclization Process Mediated by a Hypervalent Iodine Reagent.","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"","keywords":"Hypervalent molecule; Chemistry; Stereoselectivity; Reagent; Iodine; Combinatorial chemistry; Oxidative phosphorylation; Organic chemistry; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001227365,0.0005343416,0.0004116326,0.00007308117,0.0001779037,0.00005117887,0.000517505,0.0003895578,0.02794266],"category_scores_gemma":[0.0003333631,0.000534381,0.0001419188,0.0005112038,0.0002041877,0.0005574411,0.0001189709,0.0005158816,0.0003043873],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005376427,"about_ca_system_score_gemma":0.0002195397,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006117544,"about_ca_topic_score_gemma":0.000006681279,"domain_scores_codex":[0.9975839,1.237675e-7,0.0007059008,0.0005564268,0.000515137,0.0006384962],"domain_scores_gemma":[0.998063,0.0001028902,0.0005857191,0.0005432527,0.0003520866,0.0003530587],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002281943,0.0005673978,0.0003810897,0.0004730311,0.0003181024,0.000009981065,0.007101051,4.403645e-8,0.9252338,0.00001322142,0.03697218,0.02870195],"study_design_scores_gemma":[0.001098769,0.00002726076,0.0002479612,0.00009630656,0.00008958687,0.0000397625,0.003097232,0.00001768023,0.9803461,0.0000545508,0.01429774,0.0005870094],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.13615,0.00008751595,0.000001908116,0.00005138661,0.00006925599,0.000204061,0.0002940478,0.000361381,0.8627805],"genre_scores_gemma":[0.9500284,0.00006744541,0.00003573613,0.0001046565,0.0001679274,0.0001803915,0.001558624,0.00008199869,0.0477748],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.8150057,"threshold_uncertainty_score":0.9997108,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02312572239181107,"score_gpt":0.2450394872916319,"score_spread":0.2219137648998208,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}