{"id":"W2949896656","doi":"10.1002/chin.200943086","title":"ChemInform Abstract: A Synthesis of Sulfonamide Analogues of Platensimycin Employing a Palladium‐Mediated Carbonylation Strategy.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Carbonylation; Sulfonamide; Palladium; Combinatorial chemistry; Organic chemistry; Catalysis; Carbon monoxide","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003784721,0.0002878516,0.0005326465,0.0001669532,0.00004529332,0.00002154875,0.0002506567,0.000300234,0.001924289],"category_scores_gemma":[0.001448215,0.0002940615,0.0001964401,0.0004358296,0.0001164761,0.0002833886,0.00003110372,0.0001940572,0.00001150644],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001736937,"about_ca_system_score_gemma":0.0002324926,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001068528,"about_ca_topic_score_gemma":0.00001200097,"domain_scores_codex":[0.9978007,1.886982e-7,0.001092006,0.0002590848,0.0005323053,0.0003157317],"domain_scores_gemma":[0.9976189,0.0005982337,0.0007657477,0.000492028,0.0003906458,0.0001344046],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002977884,0.0001883712,0.001554812,0.000951916,0.0002052615,0.000008411461,0.0009295409,0.0001055312,0.6224872,0.0004987236,0.002612159,0.3701603],"study_design_scores_gemma":[0.0005342104,0.00002425217,0.01275507,0.0002141054,0.00008473106,0.00001536932,0.0004102066,0.0003354675,0.9840412,0.000264126,0.001032761,0.0002884861],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.231593,0.0001234028,0.00000591815,0.00005074054,0.0000522242,0.0001296892,0.0001654989,0.0001337999,0.7677457],"genre_scores_gemma":[0.9958864,0.00004950115,0.0001739282,0.00004089608,0.00009729871,0.00001379014,0.00067925,0.00002481651,0.003034077],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.7647117,"threshold_uncertainty_score":0.9999511,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02657499315615374,"score_gpt":0.2685877891048704,"score_spread":0.2420127959487166,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}