{"id":"W2949916907","doi":"10.1055/s-2003-38371","title":"Asymmetric Aldol ReactionsUsing a Fluorous Oxazolidinone Chiral Auxiliary","year":2003,"lang":"en","type":"article","venue":"Synlett","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Aldol reaction; Chiral auxiliary; Enantioselective synthesis; Organic chemistry; Combinatorial chemistry; Solid-phase synthesis; Catalysis; Peptide","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003240967,0.00061059,0.0002872794,0.0002721287,0.0002360919,0.0003446563,0.0003801853,0.0002748155,0.00118229],"category_scores_gemma":[0.0002672977,0.0001501863,0.000215567,0.0002459473,0.0002379354,0.0004731087,0.0003116493,0.0006313885,0.0007631305],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003863582,"about_ca_system_score_gemma":0.0004248186,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005002638,"about_ca_topic_score_gemma":0.001280353,"domain_scores_codex":[0.9998007,0.00002870265,0.00002299175,0.00003113737,0.00005401189,0.00006247374],"domain_scores_gemma":[0.9998153,0.00002790162,0.00005448107,0.00002432736,0.00003546568,0.00004256819],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002296896,0.00007557476,0.0003006691,0.0001824922,0.00001608334,0.0004887095,0.0001256279,0.0003859907,0.9823926,0.002514096,0.0002884486,0.01300015],"study_design_scores_gemma":[0.00001960033,0.0001561701,0.0002954109,0.000003275469,0.00001008257,0.0002803162,0.000013944,0.0004399692,0.9940742,0.0001182074,0.004576933,0.00001192874],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9213961,0.003045263,0.05592893,0.0003071355,0.0002878156,0.0001495391,0.0004916702,0.0004486405,0.01794505],"genre_scores_gemma":[0.9786284,0.001643399,0.01281263,0.00005770642,0.00003457289,0.00003175021,0.0002352302,0.00003479832,0.006521513],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00118229,"threshold_uncertainty_score":0.003955126,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01050542211934885,"score_gpt":0.2248630093436465,"score_spread":0.2143575872242977,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}