{"id":"W2949940113","doi":"10.1021/ol1026415","title":"Synthesis of Benzodiquinanes via Tandem Palladium-Catalyzed Semipinacol Rearrangement and Direct Arylation","year":2010,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":61,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Tandem; Aryl; Palladium; Catalysis; Alkyl; Combinatorial chemistry; Halogen; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002203159,0.0005377777,0.0003590978,0.0002154312,0.0002152811,0.0002188589,0.0004588447,0.0002630258,0.002091383],"category_scores_gemma":[0.000136071,0.0002496144,0.0002717045,0.0002056989,0.0002258761,0.0002483574,0.0005175102,0.0005804816,0.001380683],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002702544,"about_ca_system_score_gemma":0.000363466,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003742971,"about_ca_topic_score_gemma":0.001297479,"domain_scores_codex":[0.9998048,0.00002023635,0.00001453393,0.00004856366,0.00006232725,0.00004952607],"domain_scores_gemma":[0.9999378,0.000008062014,0.00001675209,0.000008191877,0.0000115135,0.0000176481],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000425082,0.00002116267,0.00006244989,0.0001212341,0.00001158946,0.000195972,0.00003554536,0.0001879066,0.9918297,0.0004300225,0.0001988558,0.006862927],"study_design_scores_gemma":[0.00005020971,0.0002813678,0.0005203849,0.00000604027,0.0000168998,0.0003819861,0.00001559778,0.0005261077,0.9869899,0.0001075736,0.01108598,0.00001785663],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.857035,0.009756719,0.09365264,0.0005542771,0.000341503,0.0005856739,0.001527198,0.001154525,0.0353924],"genre_scores_gemma":[0.9665077,0.003944524,0.02011386,0.0001303295,0.00004116147,0.0001631869,0.000649409,0.00006106642,0.008388759],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002091383,"threshold_uncertainty_score":0.006996334,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008898340618468349,"score_gpt":0.2292871204115258,"score_spread":0.2203887797930574,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}