{"id":"W2949977739","doi":"10.1002/chin.200141109","title":"ChemInform Abstract: First Intramolecular Geminal Acylation: Synthesis of Bridged Bicyclic Diketones.","year":2001,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Chemistry; Geminal; Intramolecular force; Acylation; Bicyclic molecule; Combinatorial chemistry; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002369653,0.0009460998,0.0004659151,0.0004559081,0.0003235028,0.0003846643,0.0008849486,0.0004772593,0.009888218],"category_scores_gemma":[0.000240276,0.0002689907,0.0003676247,0.0006945169,0.0002861499,0.0008282102,0.0008961,0.001135684,0.005532459],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005279296,"about_ca_system_score_gemma":0.0007213221,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008321746,"about_ca_topic_score_gemma":0.001642272,"domain_scores_codex":[0.9997951,0.00001861396,0.00001337161,0.00004210183,0.0000401165,0.00009063398],"domain_scores_gemma":[0.9999278,0.000006059695,0.00001019076,0.00001115684,0.000009917057,0.00003502582],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.001407702,0.0003247943,0.0003492156,0.001682457,0.0001494171,0.001397599,0.0005740607,0.002474511,0.8165085,0.01310086,0.02578604,0.1362448],"study_design_scores_gemma":[0.0002713083,0.002206347,0.001548116,0.0001119884,0.00008451293,0.001220654,0.00009952237,0.001676344,0.8854719,0.002123688,0.1050581,0.0001275172],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.6018782,0.01827725,0.1753901,0.00225403,0.004260622,0.001276576,0.01247495,0.005013525,0.1791748],"genre_scores_gemma":[0.8936979,0.0127669,0.02782581,0.0006406231,0.0001658054,0.000304337,0.004212962,0.0005140566,0.05987167],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.009888218,"threshold_uncertainty_score":0.03307945,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01572856781405311,"score_gpt":0.2558089072931958,"score_spread":0.2400803394791427,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}