{"id":"W2949982588","doi":"10.1021/ol201207b","title":"Heterocyclic Radical Mediated Synthesis and Fluorescence Properties of Conjugated Polyene Ketones","year":2011,"lang":"en","type":"article","venue":"Organic Letters","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Conjugated system; Polyene; Combinatorial chemistry; Fluorescence; Crystallization; Molecule; Photochemistry; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00013307,0.0002036952,0.0001435439,0.0001144435,0.0001428634,0.0002560272,0.0002162595,0.0001944359,0.001479615],"category_scores_gemma":[0.0001185925,0.00009361163,0.00009783632,0.0001230441,0.0001337901,0.0003057515,0.0001459401,0.0003547739,0.0003648042],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001895794,"about_ca_system_score_gemma":0.0001116826,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001615193,"about_ca_topic_score_gemma":0.0004492688,"domain_scores_codex":[0.9999205,0.00001142641,0.000007811974,0.00001631058,0.00001928251,0.0000246024],"domain_scores_gemma":[0.9999162,0.00001600864,0.00002030279,0.00001226447,0.00001441328,0.00002089232],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008105332,0.00002933648,0.00006567123,0.00005622152,0.000003806706,0.0001422456,0.00004002501,0.0002816454,0.9946948,0.0005831144,0.00004276814,0.003979321],"study_design_scores_gemma":[0.000009246861,0.0002266648,0.0006461571,0.000003008246,0.000005099759,0.00009963921,0.000008474406,0.0003215758,0.9967678,0.00005599577,0.001848815,0.000007507479],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9891877,0.001872012,0.005104854,0.00006584094,0.00004600746,0.00003294269,0.0001915479,0.00006013484,0.00343901],"genre_scores_gemma":[0.9935782,0.0009453241,0.002610966,0.00001755118,0.000009152549,0.00001776606,0.0001180355,0.00001412193,0.002688859],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001479615,"threshold_uncertainty_score":0.004949868,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02217706080565567,"score_gpt":0.196869022931823,"score_spread":0.1746919621261673,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}