{"id":"W2949982588","doi":"10.1021/ol201207b","title":"Heterocyclic Radical Mediated Synthesis and Fluorescence Properties of Conjugated Polyene Ketones","year":2011,"lang":"en","type":"article","venue":"Organic Letters","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Conjugated system; Polyene; Combinatorial chemistry; Fluorescence; Crystallization; Molecule; Photochemistry; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002475834,0.0002179151,0.0003905964,0.00006968164,0.00008689709,0.00004367734,0.0003535385,0.00009347076,0.001516898],"category_scores_gemma":[0.0002524354,0.0001642389,0.00004045023,0.0001169896,0.0006671586,0.0002799847,0.000128935,0.00006586959,0.0001846113],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000248041,"about_ca_system_score_gemma":0.00002755772,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002087862,"about_ca_topic_score_gemma":0.000007702587,"domain_scores_codex":[0.9984148,0.0001388273,0.000438229,0.0003656892,0.0002682981,0.0003742029],"domain_scores_gemma":[0.9992915,0.00005435692,0.000168287,0.0003169379,0.00004258499,0.0001263015],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000118369,0.00006424452,0.00203102,0.00009748826,0.00001479974,0.00001660685,0.0009574326,2.281401e-8,0.9963543,0.00002450266,0.0001975468,0.0001237068],"study_design_scores_gemma":[0.0002961343,0.00003924708,0.005331745,0.0001445868,0.0000368062,0.0000265103,0.00006314796,0.00000828551,0.9938162,0.000006548375,0.00002087573,0.0002099326],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9983811,0.0001527828,0.00001768079,0.0007978159,0.0003053357,0.0001956781,0.00001540609,0.0001110505,0.000023197],"genre_scores_gemma":[0.9987879,0.00008836797,0.0004955619,0.0005059565,0.00006476764,0.00001715136,0.000002672088,0.00003022014,0.000007385454],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003300725,"threshold_uncertainty_score":0.9993958,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02217706080565567,"score_gpt":0.196869022931823,"score_spread":0.1746919621261673,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}