{"id":"W2950010290","doi":"10.1002/chin.200319242","title":"Simmons—Smith Cyclopropanation Reaction","year":2003,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Cyclopropanation; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000252724,0.0006915238,0.0002465274,0.0005725002,0.0004376597,0.0003046458,0.0005154226,0.0003582346,0.01271261],"category_scores_gemma":[0.0003133182,0.0002219687,0.000266501,0.0003588409,0.0004089448,0.0008538471,0.0005810019,0.0009133135,0.003558907],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004792851,"about_ca_system_score_gemma":0.0005558213,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004923205,"about_ca_topic_score_gemma":0.0005457907,"domain_scores_codex":[0.9998748,0.00001774375,0.000006564392,0.00003451983,0.00002686218,0.00003946535],"domain_scores_gemma":[0.9999478,0.00001194212,0.000007472834,0.00001173819,0.00001142729,0.000009521309],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.001018152,0.0002643954,0.001419664,0.001267109,0.0002162968,0.002143819,0.0006629927,0.004457348,0.5558905,0.1969008,0.04177924,0.1939797],"study_design_scores_gemma":[0.00005568187,0.0003808466,0.00072949,0.00002704268,0.00004168638,0.0007538893,0.00005784027,0.002790802,0.8837052,0.009472109,0.1019488,0.00003647551],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.4472134,0.01191916,0.1064024,0.004338751,0.002251865,0.0005374381,0.001518245,0.002084133,0.4237345],"genre_scores_gemma":[0.9283245,0.005772734,0.01153695,0.0005413538,0.0001970901,0.0001319729,0.0004662858,0.00007354695,0.05295558],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.01271261,"threshold_uncertainty_score":0.04252797,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0108386484293051,"score_gpt":0.2233336499445588,"score_spread":0.2124950015152537,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}