{"id":"W2950010290","doi":"10.1002/chin.200319242","title":"Simmons—Smith Cyclopropanation Reaction","year":2003,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Cyclopropanation; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00009163373,0.0001749322,0.0001360634,0.00005995269,0.0001038495,0.00003465454,0.0001065871,0.0001637106,0.001871555],"category_scores_gemma":[0.0001642852,0.0001756549,0.00008039212,0.0001557011,0.00002511943,0.0002758089,0.00001782145,0.0002135868,0.0003475181],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002518852,"about_ca_system_score_gemma":0.00008701547,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007688677,"about_ca_topic_score_gemma":0.000008251692,"domain_scores_codex":[0.9989829,3.647755e-7,0.0002545886,0.0002274427,0.0002765196,0.0002581814],"domain_scores_gemma":[0.9992633,0.00002848941,0.0001473307,0.0003540015,0.0001033025,0.0001035592],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003016153,0.00007113061,0.0001542774,0.0002565983,0.00003431348,0.000008009473,0.0005090202,0.000001339184,0.6033949,0.00429221,0.002449598,0.3887984],"study_design_scores_gemma":[0.0002576658,0.00000565546,0.00003747441,0.00001605896,0.00001303868,0.0000474583,0.0007004028,0.000006270342,0.6434587,0.0002012404,0.3551075,0.0001484679],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.03901301,0.00008676899,0.0000227507,0.00002330624,0.0001676036,0.00006748996,0.000004874206,0.0002657387,0.9603485],"genre_scores_gemma":[0.9599018,0.00007823874,0.000351807,0.00004373964,0.0001426868,0.0000510282,0.0001026917,0.00003984303,0.0392882],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.9210603,"threshold_uncertainty_score":0.9990408,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0108386484293051,"score_gpt":0.2233336499445588,"score_spread":0.2124950015152537,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}