{"id":"W2950020775","doi":"10.1002/chin.200621183","title":"Expedient Synthesis of Cyclopropane α‐Amino Acids by the Catalytic Asymmetric Cyclopropanation of Alkenes Using Iodonium Ylides Derived from Methyl Nitroacetate.","year":2006,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Cyclopropanation; Chemistry; Cyclopropane; Catalysis; Organic chemistry; Combinatorial chemistry; Ring (chemistry)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002299366,0.000402946,0.0006042449,0.0002044617,0.0001342037,0.00003975092,0.0005213438,0.0002531263,0.0002275216],"category_scores_gemma":[0.0003339957,0.0003224273,0.0002490339,0.0005862516,0.0002249624,0.0002656305,0.0001595914,0.0002327407,0.00001203071],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003021432,"about_ca_system_score_gemma":0.0001140126,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002500082,"about_ca_topic_score_gemma":0.00006818085,"domain_scores_codex":[0.9974299,0.000004225085,0.0009888269,0.0004041926,0.000748076,0.0004247719],"domain_scores_gemma":[0.9974313,0.0004550959,0.0009608406,0.0007445638,0.000320477,0.00008769456],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000598496,0.0001101836,0.0004205561,0.0003066394,0.000133323,0.000002118641,0.0004204625,0.00002454431,0.9252632,0.00002415078,0.0002098651,0.0730251],"study_design_scores_gemma":[0.0004693719,0.00001637526,0.000408612,0.0001068104,0.0003424459,0.00002043814,0.002867198,0.0002735982,0.9938266,0.0001255243,0.001211958,0.0003310971],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.912573,0.001435602,0.0001100379,0.00003238945,0.0001272875,0.0002338748,0.0002355974,0.00009588524,0.08515634],"genre_scores_gemma":[0.9973313,0.0001281671,0.0009681367,0.000009913139,0.0001627611,0.00006834636,0.0003773567,0.0000605768,0.0008934669],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08475829,"threshold_uncertainty_score":0.9999228,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01345155828696806,"score_gpt":0.2258799574717517,"score_spread":0.2124283991847836,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}