{"id":"W2950020990","doi":"10.1002/chin.200017177","title":"ChemInform Abstract: “Breaking the Rules”: A Planar Phosphonium Cation.","year":2000,"lang":"en","type":"article","venue":"ChemInform","topic":"Molecular Junctions and Nanostructures","field":"Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Phosphonium; Planar; Service (business); Combinatorial chemistry; Polymer chemistry; Computer science; Business; Computer graphics (images)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001247391,0.0003655479,0.0003457211,0.0001725711,0.0007439457,0.0006931238,0.0009128551,0.0007165222,0.01608863],"category_scores_gemma":[0.0002549206,0.0002510058,0.0002001195,0.0002511159,0.0004230723,0.001193057,0.0010181,0.001193287,0.003968238],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000484939,"about_ca_system_score_gemma":0.0003963333,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009411438,"about_ca_topic_score_gemma":0.0008544641,"domain_scores_codex":[0.9998941,0.000008953419,0.000004012106,0.00002609979,0.00003782623,0.00002891836],"domain_scores_gemma":[0.9999715,0.000004187321,0.000004850081,0.000005474039,0.000003368061,0.00001060407],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001612517,0.0001992109,0.0003085692,0.003297168,0.00008507392,0.001844602,0.00047178,0.004651854,0.4696406,0.2014906,0.2087069,0.1076911],"study_design_scores_gemma":[0.0004077533,0.0009791409,0.0004901569,0.0001682825,0.00009945824,0.001227174,0.0002458556,0.007525853,0.4383662,0.02250327,0.5278628,0.000124137],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4965803,0.02937629,0.03579183,0.01804939,0.0204303,0.0003560712,0.003391174,0.003311888,0.3927127],"genre_scores_gemma":[0.8250615,0.01395475,0.01278106,0.00254703,0.0008256033,0.000178708,0.001989766,0.0005251638,0.1421365],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01608863,"threshold_uncertainty_score":0.05382186,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004924967802909267,"score_gpt":0.1872597295701634,"score_spread":0.1823347617672541,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}