{"id":"W2950035359","doi":"10.1021/ol0062042","title":"Tether-Controlled Cycloadditions for the Asymmetric Synthesis of Decalins:  Increased Selectivity in Acetonitrile Solvent","year":2000,"lang":"en","type":"article","venue":"Organic Letters","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Selectivity; Acetonitrile; Solvent; Solvent effects; Organic chemistry; Combinatorial chemistry; Computational chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005970084,0.0002138578,0.0005748017,0.0002417787,0.0001595051,0.00003009776,0.0004159851,0.0001230752,0.002871088],"category_scores_gemma":[0.001526001,0.0001599942,0.0003863063,0.001367252,0.00008044948,0.00007800593,0.00002647343,0.0001762341,0.00003883995],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002055053,"about_ca_system_score_gemma":0.00007990436,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004172271,"about_ca_topic_score_gemma":0.00008580623,"domain_scores_codex":[0.9984355,0.00008026151,0.0004848067,0.0003381722,0.0002986122,0.0003626276],"domain_scores_gemma":[0.9941205,0.0050445,0.0001936007,0.0005311284,0.00004540475,0.00006484434],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001137633,0.001339318,0.004658824,0.0001349718,0.001387709,0.00001022537,0.0002819655,0.0001538473,0.5213383,0.00004821245,0.007585473,0.4619235],"study_design_scores_gemma":[0.003700071,0.00002265169,0.003210925,0.00006144718,0.0006571967,0.000006816392,0.0002370193,0.001312621,0.9876518,0.00005744023,0.002740548,0.000341522],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9895287,0.0005919308,0.001058521,0.002777264,0.00004371858,0.0004867026,0.0002098001,0.00007511971,0.005228247],"genre_scores_gemma":[0.9985296,0.0001312136,0.0002145546,0.000406416,0.0001351304,0.0004220311,0.00001827277,0.00004187825,0.0001009023],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4663135,"threshold_uncertainty_score":0.9980404,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006599266877801828,"score_gpt":0.2099528065621707,"score_spread":0.2033535396843689,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}