{"id":"W2950040369","doi":"10.1139/v03-206","title":"The solid-state molecular structure of W(NO)<sub>3</sub>Cl<sub>3</sub> and the nature of its WNO bonding","year":2004,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Killam Trusts","keywords":"Chemistry; Crystallography; Intramolecular force; Bond length; Octahedron; Crystal structure; Hydrogen bond; Tungsten; Molecular geometry; X-ray crystallography; Molecule; Stereochemistry; Diffraction","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000425479,0.0001502894,0.00011654,0.00007085678,0.0001411593,0.0003445412,0.0003436997,0.0002257181,0.002112568],"category_scores_gemma":[0.0001359877,0.0001356511,0.00006785522,0.0001091437,0.0002542861,0.0002480439,0.0001501316,0.0003377717,0.0003222469],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004023088,"about_ca_system_score_gemma":0.0002448745,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001725918,"about_ca_topic_score_gemma":0.002855732,"domain_scores_codex":[0.9999791,0.000002326746,9.633868e-7,0.000004911546,0.000007495066,0.000005119918],"domain_scores_gemma":[0.9999735,0.000005325397,0.000009966862,0.000003102975,0.000003273503,0.000004821839],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004021689,0.00007797121,0.002076232,0.0003564709,0.00001593646,0.0002686601,0.0001436481,0.01227773,0.958662,0.01600961,0.001081626,0.008627977],"study_design_scores_gemma":[0.0001206794,0.0004718475,0.008846279,0.00005954747,0.00004147749,0.0004598686,0.0004665139,0.1057253,0.8489207,0.009476139,0.02534034,0.00007133951],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9930103,0.0002741836,0.003431797,0.0001096284,0.000007739838,0.000009393077,0.0003256825,0.00003930075,0.002791841],"genre_scores_gemma":[0.9954997,0.0002046319,0.00254162,0.00001930626,0.000001894887,0.00001283145,0.0005711477,0.00001865621,0.001130217],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002112568,"threshold_uncertainty_score":0.007067263,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.002199890810538477,"score_gpt":0.17845866474128,"score_spread":0.1762587739307415,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}