{"id":"W2950046317","doi":"10.1021/om800255c","title":"Iridium Complexes in Olefination Reactions","year":2008,"lang":"en","type":"article","venue":"Organometallics","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Iridium; Chemistry; Triphenylphosphine; Ethyl diazoacetate; Conjugated system; Catalysis; Organic chemistry; Medicinal chemistry; Cyclopropanation","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005312666,0.0001267024,0.0001519002,0.00014381,0.0001147095,0.00001439519,0.0001273856,0.00009618355,0.002737364],"category_scores_gemma":[0.00007005345,0.0001402363,0.00005384194,0.0003492335,0.00004494513,0.0001497297,0.00003716287,0.0002040441,0.0003521653],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002135547,"about_ca_system_score_gemma":0.00005756316,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007393974,"about_ca_topic_score_gemma":0.0000542026,"domain_scores_codex":[0.9991125,0.00001061677,0.0002512216,0.0002282605,0.0002034997,0.000193857],"domain_scores_gemma":[0.9994758,0.00003865326,0.00008838777,0.0002767073,0.00006084606,0.00005956665],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000007776999,0.0001499772,0.001981056,0.00006623876,0.00001122611,0.00002691338,0.0004523277,0.00003582043,0.9926068,0.003121273,0.00008157039,0.001458992],"study_design_scores_gemma":[0.0007293095,0.00001806402,0.009357575,0.00003344534,0.00001749029,0.0002711165,0.000706786,0.0001574311,0.8045306,0.0007012002,0.1831006,0.0003763846],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9404023,0.00008449248,0.0004336521,0.0001696569,0.0001106497,0.00005812441,0.000009765847,0.0001788349,0.05855249],"genre_scores_gemma":[0.9925048,0.0001933596,0.001223437,0.00003389585,0.00009871155,0.00001673638,0.00008550788,0.00003254037,0.005810997],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1880762,"threshold_uncertainty_score":0.9981743,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02790481788628863,"score_gpt":0.2347207688545995,"score_spread":0.2068159509683108,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}