{"id":"W2950046317","doi":"10.1021/om800255c","title":"Iridium Complexes in Olefination Reactions","year":2008,"lang":"en","type":"article","venue":"Organometallics","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Iridium; Chemistry; Triphenylphosphine; Ethyl diazoacetate; Conjugated system; Catalysis; Organic chemistry; Medicinal chemistry; Cyclopropanation","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002745646,0.0004823989,0.0002906817,0.000356167,0.0002991271,0.0004103422,0.0005287888,0.0004312565,0.001904445],"category_scores_gemma":[0.0002755407,0.0002418636,0.0002102099,0.0002244431,0.0002639098,0.0004137369,0.0004418683,0.0006111134,0.0007617453],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004493521,"about_ca_system_score_gemma":0.0001950706,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004531306,"about_ca_topic_score_gemma":0.0006380283,"domain_scores_codex":[0.9997435,0.00003733606,0.00001747548,0.00005480786,0.00005785795,0.0000889671],"domain_scores_gemma":[0.999915,0.00002303136,0.00001423441,0.00001435503,0.00001822572,0.00001520186],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001780267,0.0000360677,0.0002600622,0.0001727679,0.00001690986,0.0002753634,0.0000991033,0.0002988898,0.9880436,0.003683569,0.0002314663,0.00670414],"study_design_scores_gemma":[0.00001868711,0.00007730826,0.0001837575,0.000006568525,0.00001135193,0.0002151102,0.0000112215,0.0002012231,0.993622,0.0001655178,0.005480863,0.000006404921],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.9286916,0.009873253,0.01959724,0.0004359467,0.0001926388,0.0001712869,0.0002075384,0.0003667368,0.04046375],"genre_scores_gemma":[0.9884199,0.002195763,0.003173414,0.00004735416,0.00001381306,0.00002334472,0.0001033376,0.00002531934,0.005997797],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.001904445,"threshold_uncertainty_score":0.006371021,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02790481788628863,"score_gpt":0.2347207688545995,"score_spread":0.2068159509683108,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}