{"id":"W2950093665","doi":"10.1002/chin.200835151","title":"ChemInform Abstract: Synthesis of Morpholin‐2‐ones by Chemoselective Intramolecular Rhodium‐Catalyzed Reductive Ring Expansion of Oxazolidines.","year":2008,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Intramolecular force; Rhodium; Ring (chemistry); Catalysis; Combinatorial chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001587473,0.0008694279,0.0002573907,0.0004086046,0.0001798398,0.0003139979,0.0006709443,0.000298365,0.008106538],"category_scores_gemma":[0.000163955,0.0002739164,0.0002929167,0.0002097453,0.0002095228,0.0004805381,0.0003886978,0.0005914969,0.003389772],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004127964,"about_ca_system_score_gemma":0.000513942,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000529819,"about_ca_topic_score_gemma":0.001101801,"domain_scores_codex":[0.9999084,0.000009980556,0.000008053724,0.00002277752,0.00002000995,0.00003060228],"domain_scores_gemma":[0.9999542,0.000005540931,0.00001565981,0.000005924845,0.000005167406,0.00001362271],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005465919,0.000108383,0.000163844,0.001402512,0.00004587275,0.0009800898,0.0001648133,0.001213251,0.933907,0.006614625,0.008032582,0.04682035],"study_design_scores_gemma":[0.0002041285,0.0008430722,0.0009809881,0.00004847542,0.000044007,0.0009539257,0.00002694207,0.001182708,0.9365277,0.0006527191,0.05847796,0.00005745673],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7230473,0.02377318,0.08793383,0.001725115,0.00193538,0.00110201,0.0100181,0.005034229,0.1454308],"genre_scores_gemma":[0.9297152,0.009854633,0.02366736,0.0004234195,0.0001716618,0.0002442398,0.002518956,0.0002784469,0.03312608],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008106538,"threshold_uncertainty_score":0.02711904,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01691282978746157,"score_gpt":0.2531017576281772,"score_spread":0.2361889278407156,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}