{"id":"W2950113345","doi":"10.1002/chin.201122047","title":"ChemInform Abstract: Enantioselective Palladium‐Catalyzed Carbozincation of Cyclopropenes.","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Enantioselective synthesis; Electrophile; Catalysis; Palladium; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001588401,0.0007401761,0.000187148,0.0005507961,0.0002510094,0.0004111665,0.000633512,0.0002443891,0.009304148],"category_scores_gemma":[0.0001800117,0.0002343413,0.0001628449,0.0003386443,0.0002516657,0.0003884645,0.0004661828,0.0006424418,0.002469887],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005260878,"about_ca_system_score_gemma":0.0004868059,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001621832,"about_ca_topic_score_gemma":0.002475972,"domain_scores_codex":[0.9998517,0.00001204202,0.000007179945,0.00003362358,0.00004062002,0.00005479528],"domain_scores_gemma":[0.9999684,0.00000482433,0.000008084698,0.000005536859,0.00000588686,0.000007253603],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001174062,0.0002763331,0.0006864717,0.001103062,0.0001082419,0.001071464,0.0001925846,0.001571059,0.867965,0.01559726,0.0262023,0.08405207],"study_design_scores_gemma":[0.0001323895,0.0001487887,0.0007394553,0.00002741779,0.0000360384,0.0005925603,0.00002325478,0.0009652928,0.9636378,0.0004062953,0.03327136,0.00001926843],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5724286,0.01073401,0.07250837,0.002074118,0.001076859,0.0007261479,0.008557839,0.005541742,0.3263524],"genre_scores_gemma":[0.96287,0.004088592,0.008598297,0.000213774,0.00005440852,0.00006669515,0.0024107,0.0001403016,0.02155726],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009304148,"threshold_uncertainty_score":0.03112543,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02067160650534871,"score_gpt":0.2263118344975965,"score_spread":0.2056402279922477,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}