{"id":"W2950122729","doi":"10.1002/chin.200338182","title":"Directed ortho Metalation Approach to C‐7‐Substituted Indoles. Suzuki—Miyaura Cross Coupling and the Synthesis of Pyrrolophenanthridone Alkaloids.","year":2003,"lang":"en","type":"article","venue":"ChemInform","topic":"Coordination Chemistry and Organometallics","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Metalation; Combinatorial chemistry; Coupling (piping); Organic chemistry; Stereochemistry; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000111343,0.0003537798,0.0001958294,0.0001901381,0.000240855,0.0001659149,0.0004922757,0.0002222095,0.002250009],"category_scores_gemma":[0.00006602538,0.000195651,0.0002123489,0.0001575575,0.0002138284,0.0001998396,0.0003097842,0.0004686203,0.0009383507],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003652775,"about_ca_system_score_gemma":0.0002782136,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009236201,"about_ca_topic_score_gemma":0.002777533,"domain_scores_codex":[0.9999197,0.00001499602,0.000005512821,0.00001710093,0.00001536978,0.00002733805],"domain_scores_gemma":[0.9999757,0.000003171349,0.000006695394,0.000005096658,0.000004413491,0.000004912682],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001942903,0.0001073933,0.0001347236,0.0004246901,0.00002966513,0.0006702475,0.0001713177,0.0008060889,0.9589639,0.007219125,0.002174636,0.0291039],"study_design_scores_gemma":[0.00006652353,0.0004090362,0.0008811775,0.00002134317,0.00003558718,0.001112933,0.0000440597,0.00134231,0.9639231,0.0009434323,0.03119002,0.0000304695],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7921113,0.01362339,0.08914777,0.0009952204,0.0007058367,0.0002924711,0.000802185,0.001091902,0.1012299],"genre_scores_gemma":[0.9620173,0.004199935,0.01668316,0.0002290403,0.00004825825,0.00007105358,0.0003402424,0.00007952359,0.01633142],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002250009,"threshold_uncertainty_score":0.007527053,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01197048751849808,"score_gpt":0.2282810512867872,"score_spread":0.2163105637682891,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}